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轻型国六商用柴油车尾气N2O排放特性试验研究

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为了研究轻型国六商用柴油车尾气的氧化亚氮(N2O)排放特性,选取5台国六轻型商用柴油车进行了冷启动全球统一轻型车辆测试循环(WLTC)排放测试.结果表明:5台样车N2O比排放量均高于15 mg/km,其中1台样车的比排放量为28.8 mg/km,接近法规限值(30 mg/km);在整个测试循环中,在加减速工况下N2O排放体积分数易出现波动,峰值在1.5×10-5上下;在试验循环的前3个速度段,样车的N2O排放量水平相当,差异主要体现在超高速段;超高速段出现NH3泄漏的样车,其N2O排放量也较高,在加速工况下该车辆负荷高、排温高,原排中氮氧化物(NOx)质量分数升高,尿素喷射量增大,多余的NH3在选择性催化还原反应器(SCR)和氨气氧化催化器(ASC)中发生氧化反应,均促进了N2O的生成;在减速断油工况下,后处理管路中含氧量增加,且后处理温度下降,ASC中残余的NH3发生氧化反应,仍会促进N2O的生成,导致N2O质量分数维持在较高水平.
Experimental study on N2O emission characteristics of China Ⅵ light-duty commercial diesel vehicle
In order to study the N2O emission characteristics of China Ⅵ light-duty commercial die-sel vehicle,five China Ⅵ light-duty commercial diesel vehicles were selected for cold start world light ve-hicle test cycle(WLTC)emission testing.Results show that N2O emissions of all five vehicles exhibit were higher than 15 mg/km,with one vehicle reaching a specific emission of 28.8 mg/km,which is close to the limit of 30 mg/km.The N2O concentration tends to fluctuate under acceleration and deceleration conditions throughout the cycle,with peak values around 1.5×10-5.While the N2O emissions are compa-rable in the first three phases of WLTC,differences are primarily observed in extra high-speed phase where vehicles with NH3 leakage produce more N2O.During acceleration conditions,the vehicle has high load and exhaust temperature,resulting in an increase in NOx concentration and urea injection in the original exhaust.The excess NH3 undergoes oxidation reactions in selective catalytic reduction(SCR)re-actor and ammonia slip catalyst(ASC),which promote the generation of N2O.Additionally,under decel-eration and fuel cut-off conditions,the oxygen concertation in the post-treatment pipeline increases and the after-treatment temperature decreases.The residual NH3 in ASC undergoes oxidation reaction,which still promotes the generation of N2O and maintains a high concentration level of N2O.

light-duty diesel vehicleemission characteristicworld light-vehicle test cycle(WLTC)

王明伟

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厦门环境保护机动车污染控制技术中心,福建 厦门 361023

轻型柴油车 排放特性 全球统一轻型车辆测试循环(WLTC)

2024

柴油机设计与制造
上海柴油机股份有限公司

柴油机设计与制造

影响因子:0.156
ISSN:1671-0614
年,卷(期):2024.30(4)