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甲醇柴油微乳液制备及稳定性的实验研究

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复配油酸,二乙醇胺,span80,op-4四种表面活性剂,将其加入到加甲醇柴油混合体系中,制备甲醇柴油微乳液,并采用正交试验方法与粘度指数法,考察了制备温度,搅拌时间,搅拌速度,助表面活性剂用量,甲醇含量5种因素对甲醇柴油微乳液稳定性的影响程度.实验结果表明,当m(油酸)/m(二乙醇胺)/m( span80 )/m(OP-4)=10∶2∶3∶2时,可增溶甲醇量最大,正交试验结果表明:样品粘度指数最小,50℃恒温前后的粘度变化最小,为稳定性最佳的甲醇柴油微乳液配方,显著性检验结果表明影响因素作用程度依次为:甲醇含量>制备温度>搅拌时间>助剂用量>搅拌速度.在试验温度为30℃,搅拌时间为12 min,搅拌速度为300 r/min时,添加甲醇质量分数为5%的实验条件下制备甲醇柴油微乳液.
Experimental Study on Preparation and Stability of Methanol —Diesel Microemulsion
The methanol diescl micro-emulsion was prepared by mixing surfactants oleic acid,diethanolamine,span80,OP-4 in the methanol-diesel hybrid system.And by orthogonal experiment method and viscosity index ,the impact of preparation temperature,stirring time,stirring speed,cosurfactant dosage and methanol content on stability of the methanol diesel micro-emulsion were investigated.The experimental results show that when m(oleic acid)/m (diethanolamine)/ m (span80)/m(OP-4) = 10:2:3:2,content of dissolved methanol increases to the maximum ,viscosity index of the sample is minimum ,viscosity change is minimum at the constant temperature 50 ℃,which presents the best stability of methanol diesel micro-emulsion formula,the order of impact factors is as follows: methanol content > preparation temperature> stirring time> cosurfactant dosage> stirring speed.Methanol diesel microemulsions with best stability can be prepared under the experimental conditions of temperature 30 ℃,stirring time 12min,stirring speed 300 r/min,methanol 5.0 % (wt).

Methanol-diesel blendMicroemulsionViscosity-,Viscosity indexStability

张强强、王煊军

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第二炮兵工程大学503室,陕西 西安 710025

甲醇柴油 微乳液 动力粘度 粘度指数 稳定性

2012

当代化工
中国石油抚顺石化公司,中国石化抚顺石油化工研究院,沈阳市医药和化工行业联合会

当代化工

CSTPCD
影响因子:0.412
ISSN:1671-0460
年,卷(期):2012.41(5)
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