首页|纳米SiO2对水泥浆体孔隙和微观力学性能的影响

纳米SiO2对水泥浆体孔隙和微观力学性能的影响

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为了研究不同纳米SiO2掺量对硬化水泥浆体孔隙率与微观力学性能的影响,采用压汞实验,纳米压痕测试与GMM法获得了水泥浆体的孔隙率,压痕模量,硬度与各水化产物相的分布,并使用XRD与SEM表征了各性能最优样品的表面形貌与内部产物.试验结果表明,养护龄期为 28 天时,与空白对照组相比,当纳米SiO2的掺量质量分数为 1%、2%和 3%、4%时,水泥样品总孔隙率分别降低了 14.07%,16.67%,26.83%和7.43%,LD C-S-H与HD C-S-H的含量之和分别为对照组的99.34%,101.34%,117.48%和113.33%.但当纳米SiO2的掺量质量分数为 4%时,水泥样品的孔隙率比其他掺纳米SiO2的样品更高,且与纳米SiO2掺量质量分数为3%时相比,未水化的产物相也较多.纳米SiO2可以充分发挥成核效应和火山灰效应,生成更多的C-S-H并改变硬化水泥浆体的微观形貌,从而有效降低水泥浆体的孔隙率并提高其微观力学性能.
Effect of Nano Silica on Porosity and Micromechanical Properties of Hardened Cement Paste
In order to study the effect of different Nano SiO2 content on the porosity and micromechanical properties of hardened cement paste,the porosity,indentation modulus,hardness and phase distribution of each product of cement paste were obtained by mercury intrusion test,nano indentation test and GMM method,and the sample morphology and hydration products with the best performance were characterized by XRD and SEM.The test results show that when the curing age is 28 days,compared with the blank control group,when the content of Nano SiO2 is 1%,2%,3%and 4%,the total porosity of the cement sample decreases by 14.07%,16.67%,26.83%and 7.43%respectively,the sum of LD C-S-H and HD C-S-H was 99.34%,101.34%,117.48%and 113.33%of the control group,respectively.However,when the content of Nano SiO2 is 4%,the porosity of cement samples is higher than that of other samples doped with Nano SiO2.Compared with the content of Nano SiO2 is 3%,there are more unhydrated product phases when the content of Nano SiO2 is 4%.Nano SiO2 can give full play to the nucleation effect and pozzolanic effect,generate more C-S-H and change the micro morphology of hardened cement paste,so as to effectively reduce the porosity of cement paste and improve its micro mechanical properties.

Nano silicaCement-based materialsNanoindentationdeconvolution methodDifferent curing agePorosity

苏飞鸣、应敬伟、张向新、李劲、刘畅

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广西大学 土木建筑工程学院,广西 南宁 530004

工程防灾与结构安全教育部重点实验室,广西 南宁 530004

招商局蛇口工业区控股股份有限公司,广东 深圳 518000

悉尼科技大学 信息工程学院,悉尼 2007,澳大利亚

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纳米二氧化硅 水泥基材料 纳米压痕 解卷积方法 不同养护龄期 孔隙率

国家自然科学基金国家自然科学基金广西自然科学基金

52168015517680052018GXNSFAA281333

2024

当代化工
中国石油抚顺石化公司,中国石化抚顺石油化工研究院,沈阳市医药和化工行业联合会

当代化工

CSTPCD
影响因子:0.412
ISSN:1671-0460
年,卷(期):2024.53(2)
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