当代化工2024,Vol.53Issue(2) :300-304,499.

X65管线钢材硫化氢腐蚀影响因素分析及防护措施研究

Analysis on Influencing Factors of Hydrogen Sulfide Corrosion of X65 Pipeline Steel and Research on Protection Measures

李百虎
当代化工2024,Vol.53Issue(2) :300-304,499.

X65管线钢材硫化氢腐蚀影响因素分析及防护措施研究

Analysis on Influencing Factors of Hydrogen Sulfide Corrosion of X65 Pipeline Steel and Research on Protection Measures

李百虎1
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作者信息

  • 1. 中石油玉门油田炼化总厂,甘肃 酒泉 735200
  • 折叠

摘要

探究咪唑啉衍生物缓蚀剂在含有铁碳酸盐沉积和硫化氢的CO2 腐蚀X65管线钢材中的抑制效率.在石油和天然气工业中,使用缓蚀剂是控制碳钢在CO2 以及H2S环境中腐蚀的常见方法之一.选用咪唑啉衍生物作为缓蚀剂,通过形成保护膜来保护碳钢表面.在湿气传输管道中切取API 5L X65碳钢样品评估缓蚀剂的效果,在饱和CO2 的 3.5%(质量分数)氯化钠溶液中进行了Tafel极化和电化学阻抗谱测试.结果表明:铁碳酸盐膜的存在降低了缓蚀剂的效率.此外,实验发现在存在H2S气体的情况下,由于缓蚀剂在表面的吸附减少,抑制效果也会降低.

Abstract

The aim of this study was to investigate the inhibition efficiency of an imidazoline derivative preservative in CO2 corrosion of X65 pipeline steel containing iron carbonate deposits and hydrogen sulfide.In the oil and gas industry,the use of corrosion inhibitors is one of the common methods to control the corrosion of carbon steel in CO2 as well as H2S environments.Imidazoline derivatives were selected as corrosion inhibitors to protect the carbon steel surface by forming a protective film.A sample of API 5L X65 carbon steel was cut in a wet gas transfer pipeline.To evaluate the effectiveness of the preservative,Tafel polarization and electrochemical impedance spectroscopy tests were performed in mass fraction 3.5%NaCl solution saturated with CO2.The results showed that the presence of an iron carbonate film reduced the efficiency of the preservative.In addition,it was found that in the presence of H2S gas,the inhibition effect was reduced due to reduced adsorption of the preservative on the surface.

关键词

腐蚀/防腐/H2S腐蚀/油气管线

Key words

Corrosion/Corrosion protection/H2S corrosion/Oil and gas pipelines

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基金项目

中国石油科学研究与技术开发项目(2020B-2512)

出版年

2024
当代化工
中国石油抚顺石化公司,中国石化抚顺石油化工研究院,沈阳市医药和化工行业联合会

当代化工

CSTPCD
影响因子:0.412
ISSN:1671-0460
参考文献量17
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