首页|海上油田深部堵水用乳液增黏复合凝胶体系研究

海上油田深部堵水用乳液增黏复合凝胶体系研究

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针对海上油藏作业空间有限的特点以及传统的在线配注堵剂体系存在成胶强度低和封堵能力弱的问题,研制了一种由AMPS耐温抗盐乳液聚合物、聚乙烯亚胺(PEI)交联剂和无机纳米增强剂所组成的复合凝胶体系.通过成胶实验研究了组分质量分数、温度和矿化度对复合凝胶体系成胶性能的影响,优选了合理的配方并评价了注入和运移性能、热稳定性能和选择性封堵性能.结果表明:随着聚合物、交联剂和无机纳米增强剂组分质量分数的增加,成胶时间缩短和成胶强度增加.相比单一凝胶体系,复合凝胶体系的成胶时间缩短和强度增强.岩心注入和运移性能评价结果表明,复合凝胶体系待成胶液黏度低,能够在多孔介质中实现注入和深部运移,达到深部封堵目的.在模拟油藏温度80℃条件下,复合凝胶体系老化90 d后,脱水率仍然低于10%.该体系对不同渗透率的地层均具有良好的选择性封堵性能.
Study of Thickening Combined Gel for In-depth Water Shut off in Offshore Oilfields
In view of the limited working space and characteristics of low gelling strength and weak plugging ability of traditional online injection plugging agent system in offshore oil reservoirs,a composite gel system composed of AMPS temperature resistant and salt resistant lotion polymer,polyethyleneimine(PEI)crosslinker and inorganic nano reinforcer was developed.Through gelling experiments,the effects of component mass fraction,temperature and salinity on the gelling performance of the composite gel system were studied,the reasonable formula was optimized,and the injection and migration performance,thermal stability and selective plugging performance were evaluated.The results indicated that as the mass fraction of polymer,crosslinking agent,and inorganic nano-reinforcing agent increased,the gelation time decreased and the gelation strength increased.Compared with single gel system,composite gel system had shorter gel forming time and stronger strength.The results based on core injection and migration performance showed that the viscosity of the compound gel system to be formed was low,and it could achieve injection and deep migration in porous media to achieve the purpose of deep plugging.At the simulated reservoir temperature of 80℃,the dehydration rate of composite gel system was still lower than 10%after 90 d aging.This system had good selective sealing performance for formations with different permeability.

Offshore reservoirsIn-depth water shutoffcombined gelBulk gelationPerformance evaluation

刘帅、吴意明、王晨、张珂、徐国瑞、常振

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中海石油(中国)有限公司深圳分公司,广东 深圳 518000

中海油田服务股份有限公司,天津 300459

海上油藏 深部堵水 复合凝胶 静态成胶 性能评价

中国海洋石油集团公司重大专项(十四五)

CCL2022SZPS0276

2024

当代化工
中国石油抚顺石化公司,中国石化抚顺石油化工研究院,沈阳市医药和化工行业联合会

当代化工

CSTPCD
影响因子:0.412
ISSN:1671-0460
年,卷(期):2024.53(2)
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