首页|Ag3PO4/GO/Bi2MoO6复合材料的制备及用于尾矿废水中黄药的高效降解

Ag3PO4/GO/Bi2MoO6复合材料的制备及用于尾矿废水中黄药的高效降解

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用两步水热法合成了Ag3PO4/GO/Bi2MoO6 三元复合材料.通过控制GO与Ag3PO4 前驱体的添加量,制备出一系列不同负载比的 Ag3PO4/GO/Bi2MoO6 复合材料,以乙基黄药为目标降解物评价其光催化性能.同时采用FT-IR、SEM和UV-vis等手段表征复合材料的微观形貌及光学性能.结果表明:与Bi2MoO6 和GO/Bi2MoO6相比,Ag3PO4/GO/Bi2MoO6复合材料的光催化活性显著提高,当GO添加量为5 mg、Ag3PO4前驱体添加量为 8 mmol时,其光催化速率约为GO/Bi2MoO6 的 7.6 倍,是Bi2MoO6 的 34.0 倍.此外,同实验条件下,循环利用5次后Ag3PO4/GO/Bi2MoO6复合材料降解率仍保持良好的稳定性.
Preparation of Ag3PO4/GO/Bi2MoO6 Composite Material and Efficient Eegradation of Xanthate in Tailings Wastewater
Ag3PO4/GO/Bi2MoO6 ternary composite material was synthesized using a two-step hydrothermal method.By controlling the amount of GO and Ag3PO4 precursor added,a series of Ag3PO4/GO/Bi2MoO6 composite materials with different loading ratios were prepared,and their photocatalytic performance was evaluated with ethyl xanthate as the target degradation product.Simultaneously,FT-IR,SEMand UV-vis methods were used to characterize the microstructure and optical properties of the composite material.The results showed that compared with Bi2MoO6 and GO/Bi2MoO6,the photocatalytic activity of Ag3PO4/GO/Bi2MoO6 composite material was significantly improved when the GO addition was 5 mg;When the amount of Ag3PO4 precursor added was 8 mmol,its photocatalytic rate was about 7.6 times that of GO/Bi2MoO6 and 34.0 times that of Bi2MoO6.In addition,under the same experimental conditions,the degradation rate of Ag3PO4/GO/Bi2MoO6 composite material remained stable after 5 cycles of recycling.

PhotocatalysisGOBi2MoO6Ag3PO4

徐珊、袁澳铧、张宁、段雨柔、任柳昕

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商洛学院 化学工程与现代材料学院,陕西省尾矿资源综合利用重点实验室,陕西省矿产资源清洁高效转化与新材料工程研究中心,陕西 商洛 726000

光催化 GO Bi2MoO6 Ag3PO4

陕西省大学生创新创业训练计划商洛市科技计划商洛学院服务地方专项

S202111396043SK2019-8221FK003

2024

当代化工
中国石油抚顺石化公司,中国石化抚顺石油化工研究院,沈阳市医药和化工行业联合会

当代化工

CSTPCD
影响因子:0.412
ISSN:1671-0460
年,卷(期):2024.53(2)
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