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急冷系统运行问题与优化措施探讨

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某石化 80 万 t·a-1 乙烯装置采用美国 S&W 公司专利技术,前脱丙烷前加氢,设计年操作时间为8 000 h,装置的操作弹性60%~110%.介绍了急冷系统中的裂解汽油干点过高、稀释蒸汽发生器频繁泄漏以及急冷水一级冷却器泄漏的问题,通过数据建模、压力和pH值分析、扫描电子显微镜分析、金相分析等手段找出其导致问题产生的原因,并提出了调整急冷油塔侧线采出量、增加pH值APC调节系统、增加工艺水甲苯萃取装置、外管壁渗硼工艺处理、对换热器设置阳极保护等技术建议以解决这些问题,来提高急冷系统的稳定性和长期运行性.
Discussion on Operation Issues and Optimization Measures of Rapid Cooling System
800 kt·a-1 Ethylene unit in a petrochemical company uses patented technology from the US-based S&W company,operates with a designed annual operating time of 8 000 h.The plant's operational flexibility ranges from 60%to 110%.In this paper,issues in the quench system were discussed,including high dry point of cracked gasoline,frequent leaks in the dilution steam generator,and leaks in the first-stage cooling of the quench water.By employing methods such as data modeling,pressure-pH analysis,scanning electron microscopy,and metallographic analysis,the root causes of these problems were identified.Technical suggestions were presented,such as adjusting the side-stream extraction rate of the quench tower,implementing a pH value advanced process control system,adding a toluene extraction unit for the process water,applying an external boron infiltration process to the outer tube wall,and introducing anodic protection in heat exchangers,in order to enhance the stability and long-term performance of the quench system.

Rapid cooling systemHeat exchanger leakageCracked gasoline dry pointUnder-deposit corrosion

于洋、张勇、尤越

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中国石油天然气股份有限公司抚顺石化分公司烯烃厂,辽宁 抚顺 113001

急冷系统 换热器泄漏 裂解汽油干点 腐蚀

2024

当代化工
中国石油抚顺石化公司,中国石化抚顺石油化工研究院,沈阳市医药和化工行业联合会

当代化工

CSTPCD
影响因子:0.412
ISSN:1671-0460
年,卷(期):2024.53(2)
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