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清洗剥离操作对循环水系统的影响

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某石化公司循环水场由于换热器发生泄漏情况,滋生大量生物黏泥附着在设备及管道上,降低了循环水流速,并生成厌氧菌,导致换热设备进一步腐蚀泄漏,造成恶性循环.大型循环水系统出现水质问题后很难在短时间内恢复,导致换热设备进一步加速腐蚀,为应对这种情况,该公司为循环水装置开发出一种新式杀菌剥离技术,可迅速缓解生物黏泥对水质的影响.对循环水系统进行杀菌处理投加双季铵盐及次氯酸钠等药剂,该药剂具有高效、低毒、成本低、不易受pH值变化的影响、使用方便、对生物黏泥层有较强的剥离作用、化学性能稳定、分散及缓蚀作用较好等特点,通过停塔抽沫、备泵扰动、置换排放等一系列措施,大幅度降低生物黏泥,保证生产装置平稳高负荷运行.
Effect of Cleaning and Stripping Operation on Circulating Water System
Due to the leakage of the heat exchanger in the circulating water field of a petrochemical company,a large number of biological mud was generated to adhere to the equipment and pipelines,reducing the flow rate of circulating water,and generating anaerobic bacteria,resulting in further corrosion and leakage of heat exchange equipment,resulting in a vicious cycle.It is difficult to recover in a short period of time after water quality issues occur in large-scale circulating water systems,leading to further accelerated corrosion of heat exchange equipment.To cope with this situation,the company developed a new sterilization and stripping technology for circulating water equipment,adding biquaternary ammonium salt and sodium hypochlorite and other agents to the circulating water system for sterilization treatment.The agent has the characteristics of high efficiency,low toxicity,not easy to be affected by the change of pH value,easy to use,strong peeling effect on the biological clay layer,stable chemical properties,dispersion and corrosion inhibition.Through a series of measures such as stopping the tower and pumping,starting the standby pump,displacing and discharging,the biological mud can be greatly reduced to ensure the stable and high load operation of the production unit.

Circulating waterCleaning and strippingSodium hypochloriteQuaternary ammonium salt

李家乐、谭克、王顺平、刘非、凌霄、贾俊杰、刘国辉

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中国石油抚顺石化公司烯烃厂,辽宁 抚顺 113008

循环水 清洗剥离 次氯酸钠 双季铵盐

2024

当代化工
中国石油抚顺石化公司,中国石化抚顺石油化工研究院,沈阳市医药和化工行业联合会

当代化工

CSTPCD
影响因子:0.412
ISSN:1671-0460
年,卷(期):2024.53(2)
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