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强化混凝沉淀法处理生活垃圾渗滤液实验研究

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采用 Fenton 和絮凝处理的结合方式处理广东垃圾填埋场的滤液.实验采用不同的 Fenton 处理条件,包括 pH 值、H2O2/Fe(Ⅱ)比例和用量以及反应时间,以确定最佳的处理条件.在最佳 Fenton 处理条件下,COD去除效率约为80%,进水质量浓度为624±80 mg·L-1,符合QCVN 25:2009/BTNMT的要求.同时去除了75%的色度、25%的氨和12%的悬浮物,为下一阶段的絮凝处理创造了有利条件.在絮凝方面,研究使用CaO和聚合氯化铝(PAC)顺序处理滤液.经过CaO(6 g·L-1,180 min)、PAC(1 500 mg·L-1)和A101(2 mg·L-1)处理后,COD、色度、氨和悬浮物的去除率分别达到85%、99%、99%~99.5%和88%,出水可满足排放标准,毒性分析表明Fenton处理降低了垃圾填埋场渗滤液的毒性.
Experimental Study on Treatment of Domestic Waste Leachate by Intensive Coagulation and Sedimentation Method
The combination of Fenton and flocculation treatment was used to treat the filtrate from a landfill in Guangdong.Different Fenton treatment conditions,including pH,H2O2/Fe(Ⅱ)ratio and dosage,and reaction time,were used to determine the optimal treatment process.Under the optimal Fenton treatment conditions,the COD removal rate was about 80%,and the influent mass concentration was 624±80 mg·L-1,which met the requirements of QCVN 25:2009/BTNMT.Meanwhile,75%of the color,25%of the ammonia and 12%of the suspended matter were removed,creating favorable conditions for the next stage of flocculation treatment.For flocculation,CaO and polymeric aluminum chloride(PAC)were used to sequentially treat the filtrate.After treatment with CaO(6 g·L-1 and 180 min),PAC(1 500 mg·L-1)and A101(2 mg·L-1),the removal rates of COD,color,ammonia and suspended matter reached 85%,99%,99%~99.5%and 88%,respectively,and the effluent could meet the treatment requirements of the discharge standard,and the toxicity analysis showed that both Fenton treatment reduced the toxicity of landfill leachate.

FentonFlocculationWastewater treatmentLeachate

李国浩

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肇庆市高要区开放大学,广东 肇庆 526100

Fenton 絮凝 污水处理 渗滤液

国家自然科学基金

51378129

2024

当代化工
中国石油抚顺石化公司,中国石化抚顺石油化工研究院,沈阳市医药和化工行业联合会

当代化工

CSTPCD
影响因子:0.412
ISSN:1671-0460
年,卷(期):2024.53(3)
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