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还原氧化石墨烯亲油疏水材料的制备及性能评价

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石墨烯类材料作为理想的碳纳米材料具有三维网状空间结构、巨大的比表面积和良好亲油疏水性能,被广泛应用于增强高分子材料.介绍了氧化石墨烯发泡法制备吸油材料,即聚氨酯材料在发泡过程中加入氧化石墨烯(GO)改性剂,随后对其还原,制备还原氧化石墨烯亲油疏水材料,并进行了结构表征及室内评价,重点探讨了氧化石墨烯浓度对材料吸附性能的影响,材料亲油疏水性能以及静态、动态油水分离效率.同时,对比总结其他石墨烯改性吸油材料的优缺点及目前存在的问题,最后概括本方法制备吸油材料的技术优势,为GO/CNTs等纳米材料制备高附加值产品工业化提供参考.
Preparation and Performance Evaluation of Reduced Graphene Oxide Hydrophilic and Hydrophobic Materials
As an ideal carbon nano material having a three-dimensional network spatial structure,huge specific surface area and good lipophilic and hydrophobic properties,graphene materials are widely used in reinforced polymer materials.In this article,the preparation of oil absorbing materials was introduced by using graphene oxide foaming method,adding graphene oxide(GO)modifiers to polyurethane materials during the foaming process,and then reducing them to prepare reduced graphene oxide oleophilic and hydrophobic materials.The structural characterization and indoor evaluation were carried out with a focus on exploring the influence of graphene oxide concentration on the adsorption performance of the material,the oleophilic and hydrophobic properties of the material,and the static and dynamic oil-water separation efficiency.The advantages and disadvantages of other graphene modified oil absorbing materials,as well as the current problems,were compared and summarized.Finally,the technical advantages of this method were summarized,providing reference for the industrialization of preparing high value-added products using nanomaterials such as GO/CNTs.

PolyurethaneGrapheneOleophobic and hydrophobicAdsorption performanceSynthesisPerformance evaluation

周柄男、丁秋炜、张宇、张昕、滕大勇、王昊、王超

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中海油能源发展股份有限公司工程技术分公司,天津 300450

中海油天津化工研究设计院有限公司,天津 300131

聚氨酯 石墨烯 亲油疏水 吸附性能 合成 性能评价

中海油能源发展股份有限公司重大专项子课题

HFKJ-ZDGG-TJY-2021-07

2024

当代化工
中国石油抚顺石化公司,中国石化抚顺石油化工研究院,沈阳市医药和化工行业联合会

当代化工

CSTPCD
影响因子:0.412
ISSN:1671-0460
年,卷(期):2024.53(4)
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