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基于碳氮稳定同位素特征差异的三七真伪判别

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利用稳定同位素质谱技术,分析三七及其伪品(莪术、姜黄、菊叶三七、竹节参、水三七、景天三七)的碳、氮稳定同位素比值特征,探讨该技术用于三七真伪判别的可行性.建立元素分析-稳定同位素质谱法,测定三七、三七伪品中δ13C值、δ15N值,结果表明三七与伪品δ13C值有显著差异(P<0.05).通过测定三七、三七伪品中δ13C值这一关键鉴别因子,结合δ15N值,可将三七与这几类伪品分开;对随机购买的三七粉样品的真伪鉴别结果表明,稳定同位素质谱技术能有效鉴别三七真伪,可用于对市售三七类中药材的真伪鉴别,以期为三七类制品的质量安全提供技术支撑.
Identification of Panax notoginseng Based on the Difference of Stable Isotope Characteristics of Carbon and Nitrogen
To explore the feasibility of using IRMS for the authenticity identification of Panax notoginseng,the characteristics of stable isotopes of carbon and nitrogen of Panax notoginseng and its counterfeits(Curcuma zedoaria, Curcuma longa, Chrysanthemum leaf Sanqi, Bamboo-like Dendrobium, Water Sanqi, Sedum Sanqi) were analyzed. A element analysis-isotope ratio mass spectrometry method was established to measure the isotope ratios of δ13C and δ15N in Panax notoginseng and its counterfeits. Variance analysis showed significant differences in the stable isotope δ13C values between Panax notoginseng and its counterfeits (P<0.05). Cluster analysis indicated that the determination of δ13C,combined with δ15N,could separate Panax notoginseng from the counterfeits. The isotope ratio mass spectrometry method, by measuring and identification the Panax notoginseng power purchased at random,could effectively identify the authenticity of Panax notoginseng.The method developed in this study can be used to trace the truth of Panax notoginseng products,which will provide technical support for ensuring food safety.

Panax notoginsengStable isotopes of carbon and nitrogenIsotope mass spectrometryTrue and false identification

王海燕、范稚莉、冯家望、明荔莉、唐梓意

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拱北海关技术中心,广东珠海 519000

三七 碳氮稳定同位素 同位素质谱技术 真伪判别

拱北海关科技计划项目海关总署科技计划项目珠海市科技计划项目拱北海关科技计划项目

2021GK0122022Hk03222200040003522023GK013

2024

当代化工
中国石油抚顺石化公司,中国石化抚顺石油化工研究院,沈阳市医药和化工行业联合会

当代化工

CSTPCD
影响因子:0.412
ISSN:1671-0460
年,卷(期):2024.53(5)
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