首页|Nb2O5/Nb2C催化剂的制备及其光催化NO转化的性能

Nb2O5/Nb2C催化剂的制备及其光催化NO转化的性能

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采用焙烧法原位构建Nb2O5/Nb2C异质样品,通过XRD、Raman、SEM、BET、UV-Vis DRS、Mott-Schottky及EIS等技术对样品的结构及性质进行分析,以NO为目标污染物评价其光催化活性.结果表明:Nb2O5/Nb2C异质样品能够提供较多的反应活性位点、提高光的利用率及光生电子和空穴的分离效率,进而提高其光催化活性;在模拟太阳光照射下,其对NO的转化率达到了50.5%,分别为Nb2O5和Nb2C样品的2.4倍和14.4倍,且在NO转化过程中,NO2选择性转化率仅为0.75%.
Preparation of Nb2O5/Nb2C Catalyst and Its Photocatalytic Performance for NO Conversion
Nb2O5/Nb2C heterojunction was successfully in-situ constructed through calcination method. The structureand properties of synthesized samples were analyzed using techniques such as XRD, Raman, SEM, BET, UV-Vis DRS, Mott-Schottky, and EIS. NO was selected as the target pollutant to evaluate its photocatalytic activity. The research results showed that the Nb2O5/Nb2C heterojunction could provide more reactive sites, improve light utilization efficiency and the separation efficiency of photo generated electrons and holes, thereby enhancing its photocatalytic activity. Under simulated sunlight irradiation, the conversion rate of NO reached 50.5%, which was 2.4 times and 14.4 times higher than that of Nb2O5 and Nb2C samples, respectively. In NO conversion experiment, the selective conversion rate of NO2 was only 0.75%.

Nb2O5/Nb2CPhotocatalysisNO conversionCompositesEnvironmentCatalyst

王静、李喜兰、丘宇锴、刘续兴、陈成志

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珠海科技学院应用化学与材料学院,广东珠海 519040

Nb2O5/Nb2C 光催化 NO转化 复合材料 环境 催化剂

广东省高校科研平台项目(青年创新人才类)珠海科技学院创新能力工程项目

2022KQNCX1452019XJCQ016

2024

当代化工
中国石油抚顺石化公司,中国石化抚顺石油化工研究院,沈阳市医药和化工行业联合会

当代化工

CSTPCD
影响因子:0.412
ISSN:1671-0460
年,卷(期):2024.53(5)
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