当代化工2024,Vol.53Issue(7) :1550-1554.

改性纳米SiO2颗粒提高CO2泡沫稳定性

Study on Improving the Stability of CO2 Foam by Modified Nano-silica Particles

宁创 张丽伟 童长兵 景正正
当代化工2024,Vol.53Issue(7) :1550-1554.

改性纳米SiO2颗粒提高CO2泡沫稳定性

Study on Improving the Stability of CO2 Foam by Modified Nano-silica Particles

宁创 1张丽伟 1童长兵 1景正正1
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作者信息

  • 1. 延长油田股份有限公司宝塔采油厂,陕西 延安 716000
  • 折叠

摘要

泡沫注入作为一种提高采收率的方法,其稳定性和改善泡沫从裂缝向基质的运移一直是裂缝性油藏泡沫注入领域的2个主要问题.使用3-氨基丙基三乙氧基硅烷(APTES)对二氧化硅纳米颗粒进行改性来稳定二氧化碳泡沫,选择FTIR分析和接触角测量表征泡沫的产生和稳定性.实验在不同质量分数的NPs(0.04%~0.20%)、2种质量分数的SDS(0.236%~0.472%)、存在和不存在MgCl2 盐的情况下进行.结果表明:APTES对二氧化硅进行表面改性后,纳米颗粒在油水体系中更亲油,在空气-水体系中更亲气.这反过来又放大了改性二氧化硅(MS)向水气界面的迁移,增强了CO2 泡沫的稳定性.泡沫稳定性实验证实了这一机制的存在,将泡沫稳定剂从二氧化硅切换到MS纳米颗粒导致泡沫最大半衰期增加33.3%.泡沫性不受NPs类型的影响;然而,由于SDS在纳米颗粒表面的吸附,泡沫性降低.

Abstract

As a method to enhance oil recovery,the stability of foam injection and the improvement of foam migration from fracture to matrix have been two major problems in the field of foam injection in fractured reservoirs.3-aminopropyl triethoxysilane(APTES)was used to modify silica nanoparticles to stabilize carbon dioxide foam,and FTIR analysis and contact angle measurement were selected to characterize foam generation and stability.The experiment was conducted with different mass fractions of NPs(0.04%~0.20%),two mass fractions of SDS(0.236%~0.472%),and the presence and absence of MgCl2 salt.The results showed that after surface modification of silica by APTES,the nanoparticles were more oil-philic in oil-water system and more gas-philic in air-water system.This,in turn,the migration of the modified silica(MS)to the water-gas interface was amplified to enhance the stability of the CO2 foam.Foam stability experiments confirmed the existence of this mechanism,and switching the foam stabilizer from silica to MS nanoparticles resulted in a 33.3%increase in the maximum foam half-life.Foam property was not affected by NPs type.However,the foamability was reduced due to the surface adsorption of SDS on the nanoparticle surface.

关键词

泡沫稳定性/起泡性/CO2泡沫/表面改性SiO2

Key words

Foam stability/Foaming property/CO2 foam/Surface modified SiO2

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基金项目

国家自然基金青年基金项目(41702146)

出版年

2024
当代化工
中国石油抚顺石化公司,中国石化抚顺石油化工研究院,沈阳市医药和化工行业联合会

当代化工

CSTPCD
影响因子:0.412
ISSN:1671-0460
参考文献量18
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