当代化工2024,Vol.53Issue(7) :1609-1613.

油田采出天然气低温析烃能力实验及化学机理研究

Experimental Study on Hydrocarbon Evolution Ability of Natural Gas Produced in Oilfield at Low Temperature and Its Chemical Mechanism

余洁 张照健 陈璐 杨玥瑢 吕海娥
当代化工2024,Vol.53Issue(7) :1609-1613.

油田采出天然气低温析烃能力实验及化学机理研究

Experimental Study on Hydrocarbon Evolution Ability of Natural Gas Produced in Oilfield at Low Temperature and Its Chemical Mechanism

余洁 1张照健 2陈璐 1杨玥瑢 2吕海娥1
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作者信息

  • 1. 玉门油田老君庙采油厂,甘肃酒泉 735019
  • 2. 玉门油田生产保障服务中心,甘肃酒泉 735019
  • 折叠

摘要

随着全球对清洁能源的需求不断增长,天然气的有效利用成为能源研究的关键领域.通过气相色 谱-质谱联用技术(GC-MS)对油田天然气样品进行了气体组分的定性定量分析,并建立了适用于低温条件的动力学模型.研究发现,在温度 20~80℃和压力 0.1~10 MPa的条件下,甲烷的摩尔分数随温度升高而增加,而乙烷和丙烷的摩尔分数则随温度升高而减少.甲烷的反应速率常数在不同温度下变化不大(0.0746~0.0517),表明其在低温条件下相对稳定.而乙烷和丙烷的反应速率常数随温度和压力的增加而显著提高,反映出它们对环境变化更敏感.此外,深入探讨了温度和压力对这些烃类反应的综合影响,揭示了在不同环境条件下的化学转化机理.研究结论对于优化天然气加工工艺,特别是在低温条件下的处理和转化策略具有重要意义.

Abstract

As the global demand for clean energy continues to grow,the efficient utilization of natural gas has become a key area of energy research.In this paper,gas chromatography-mass spectrometry(GC-MS)was used to conduct qualitative and quantitative analysis of gas components in oil field natural gas samples,and a kinetic model suitable for low-temperature conditions was established.The study found that in the temperature range of 20℃ to 80℃ and the pressure of 0.1 MPa to 10 MPa,the mole fraction of methane increased with increasing of temperature,while the mole fractions of ethane and propane decreased with increasing of temperature.The reaction rate constant of methane did not change much at different temperatures(0.0746 to 0.0517),indicating that it was relatively stable under low temperature conditions.The reaction rate constants of ethane and propane increased significantly with increasing of temperature and pressure,reflecting that they were more sensitive to environmental changes.In addition,this study further explored the combined effects of temperature and pressure on the reactions of these hydrocarbons,revealing the chemical transformation mechanisms under different environmental conditions.The conclusions of this study are of great significance for optimizing natural gas processing technology,especially processing and conversion strategies under low temperature conditions.

关键词

油田采出气/低温析烃/天然气动力学/化学机理

Key words

Natural gas produced in oilfield/Low temperature hydrocarbon evolution/Natural gas dynamics/Chemical mechanism

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基金项目

国家科技重大专项项目(2021ZX05020-002)

出版年

2024
当代化工
中国石油抚顺石化公司,中国石化抚顺石油化工研究院,沈阳市医药和化工行业联合会

当代化工

CSTPCD
影响因子:0.412
ISSN:1671-0460
参考文献量9
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