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糠醇选择性加氢制备1,2-戊二醇

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糠醇选择性加氢制备 1,2-戊二醇是一种复杂的化学反应,存在选择性差、副产多、成本高等问题.合成了一种新型Cu-CLXC催化剂,在固定床模式及温和条件下(反应温度 160℃、反应压力5 MPa、空速0.3 h-1)对糠醇加氢表现出优异的催化活性,原料转化率>99.9%,1,2-戊二醇选择性>60.0%,并且该催化剂连续运行2000 h后活性未见下降趋势,催化活性及稳定性远高于现有报道的催化剂水平.
Selective Hydrogenation of Furfuryl Alcohol to 1,2-Pentanediol
Selective hydrogenation of furfuryl alcohol to 1,2-pentanediol is a complex reaction,which has many problems such as poor selectivity,high by-product and high cost.A new Cu-CLXC catalyst was synthesized and showed excellent catalytic activity for hydrogenation of furfuryl alcohol in a fixed bed reactor under mild conditions(reaction temperature 160℃,reaction pressure 5 MPa,airspeed 0.3 h-1),the conversion of raw materials was>99.9%and the selectivity of 1,2-pentanediol was>60.0%,the activity and stability of the catalyst were higher than that of the reported catalysts after running for 2000 h.

1,2-PentanediolFixed bedReactivityProductionStability

罗文星、汪永军、向明林、周冬京、邱长玖

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湖南长炼新材料科技股份公司,湖南 岳阳 414012

1,2-戊二醇 固定床 活性 生产 稳定性

2024

当代化工
中国石油抚顺石化公司,中国石化抚顺石油化工研究院,沈阳市医药和化工行业联合会

当代化工

CSTPCD
影响因子:0.412
ISSN:1671-0460
年,卷(期):2024.53(7)
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