当代化工2024,Vol.53Issue(9) :2031-2035.

改性纳米流体的化学性能测试与驱油特性评价

Chemical Performance Testing and Oil Displacement Performance Evaluation of Modified Nanofluids

朱灵 张莉莹 沈玺琳 曹琳 李超 曾家明
当代化工2024,Vol.53Issue(9) :2031-2035.

改性纳米流体的化学性能测试与驱油特性评价

Chemical Performance Testing and Oil Displacement Performance Evaluation of Modified Nanofluids

朱灵 1张莉莹 1沈玺琳 1曹琳 2李超 3曾家明4
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作者信息

  • 1. 中国石油玉门油田分公司老君庙采油厂,甘肃酒泉 735200
  • 2. 中国石油青海油田勘探开发研究院,甘肃敦煌 736202
  • 3. 中国石油青海油田分公司采油三厂,青海茫崖 816499
  • 4. 中国石油青海油田分公司采油五厂,青海海西 816400
  • 折叠

摘要

基于表面活性剂改性制备了一种稳定性良好的纳米流体,结合微观测试分析了其相关化学性能与流体特性,评价了改性纳米流体在提高原油采收率方面的驱替效用.结果表明:纳米SiO2改性表面活性剂物理吸附行为(PAN)流体是化学键合的化学反应,表面活性剂改性PAN为表面活性剂的物理吸附行为,改性后纳米颗粒表面从亲水性转变为疏水性.表面活性剂的连接作用可强化油水分子间的作用力,降低界面处自由能,使得PAN-B与PAN-C体系的界面张力迅速降至10 mN·m-1以下.油水质量比显著影响Pickering乳液的形态与稳定性.PAN-B体系的乳状液性能最优,其完全破乳时间可达48 h以上.质量分数为0.1%的PAN-B纳米流体时原油采收率增幅最大,且采收率会随注入速率或注入体积的增加先增加而后降低.

Abstract

A kind of stable nanofluid was prepared based on surfactant modification,and its related chemical and fluid properties were analyzed through microscopic testing.The displacement effect of modified nanofluids in improving crude oil recovery was evaluated.The results indicated that the modification of PAN fluid with nano SiO2 was a chemical bonding reaction,and surfactant-modification of PAN was the physical adsorption behavior of surfactant,and the surface of nanoparticles changed from hydrophilicity to hydrophobicity after modification.The linking effect of surfactants enhanced the interaction between oil-water molecules,reduced the free energy at the interface,and rapidly reduced the interfacial tension of the PAN-B and PAN-C systems to below 10 mN·m-1.Oil-water mass ratio significantly affected the morphology and stability of Pickering lotion.The PAN-B system had the best emulsion performance,with a complete demulsification time of over 48 h.When the mass fraction of PAN-B nanofluid was 0.1%,the increase in crude oil recovery rate was the largest,and the recovery rate first increased and then decreased with the increase of injection rate or injection volume.

关键词

表面活性剂/纳米材料/回收/复杂流体/化学反应/石油

Key words

Surfactants/Nanomaterials/Recovery/Complex fluid/Chemical reaction/Petroleum

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基金项目

国家自然科学基金重点项目(52334001)

中国石油天然气股份有限公司科研项目(2023E-03-01)

出版年

2024
当代化工
中国石油抚顺石化公司,中国石化抚顺石油化工研究院,沈阳市医药和化工行业联合会

当代化工

CSTPCD
影响因子:0.412
ISSN:1671-0460
参考文献量19
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