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延长油田转向酸油层深部解堵室内评价

Indoor Evaluation of Deep Plugging Removal of Steering Sour Oil Formation in Yanchang Oilfield

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酸化常用于解除伤害和增加储层渗透率.在碳酸盐岩储层中,这一过程通常采用基于黏弹性表面活性剂(VES)的转向酸.VES转向酸配方可以对[H+]和[Ca2+]的变化做出响应,从而调节表面活性剂溶液的流变性.当黏度增加时,流体会改变其流动方向,形成虫洞.构建了酸液中和的体系,并使用2种商用转向酸进行了测试,研究了不同中和度下流体的流变性,模拟了流体在碳酸盐基质中流动和反应时的行为.此外,还研制了基于VES的新型响应性转向酸ZX,并研究了它们在不同[H+]和[Ca2+]下的线性和非线性流变性,并在岩心驱替实验中评估了其性能,实验结果表明新型转向酸形成了优势虫洞.
Acidizing is commonly used to relieve damage and increase reservoir permeability.In carbonate reservoirs,this process is commonly performed using viscoelastic surfactant (VES)-based steering acids.VES steering acid formulations can respond to changes in[H⁺]and[Ca²⁺]to modulate the rheology of the surfactant solution.When the viscosity increases,the fluid changes its flow direction and forms wormholes.In this paper,a system for acid-liquid neutralization was constructed and tested using two commercial steering acids to investigate the rheology of the fluid at different degrees of neutralization and to simulate the behavior of the fluid as it flowed and reacted in a carbonate matrix.In addition,new responsive steering acids based on VES,named ZX,were developed and their linear and nonlinear rheology was investigated at different[H⁺]and[Ca²⁺],and their performance was evaluated in core replacement experiments.The experimental results showed that these novel steering acids formed desirable dominant wormholes.

Steering acidsSurfactantsAcidificationPlugging removalResponsivenessInterfaceInterfacial rheologySurfactants

李延生、王建新、张军、李明、张刚

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延长油田股份有限公司杏子川采油厂,陕西安塞 717499

延长油田股份有限公司富县采油厂,陕西富县 7275900

延安盛科工贸有限公司,陕西延安 716000

长庆油田分公司工程监督处乌审旗总监站,内蒙古乌审旗 017300

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转向酸 表面活性剂 酸化 解堵 响应性 界面 界面流变学 表面活性剂

陕西省教育厅科技专项计划项目

2024JDTD0018

2024

当代化工
中国石油抚顺石化公司,中国石化抚顺石油化工研究院,沈阳市医药和化工行业联合会

当代化工

CSTPCD
影响因子:0.412
ISSN:1671-0460
年,卷(期):2024.53(9)
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