首页|CuO/活性炭催化湿式氧化甲基橙废水的研究

CuO/活性炭催化湿式氧化甲基橙废水的研究

Study on Wet Oxidation of Methyl Orange Wastewater Catalyzed by CuO/Activated Carbon

扫码查看
基于以硝酸铜为活性组分的前驱物,采取浸渍焙烧法制备了CuO/活性炭催化剂,并以H2O2为氧化剂,对比了在常压条件下催化湿式氧化工艺中处理质量浓度500 mg·L-1甲基橙模拟废水的效果,分别考察了不同CuO/活性炭催化剂加入量、质量分数30%的H2O2氧化剂用量、脱色反应时间、脱色反应温度对甲基橙废水脱色率的影响.结果表明:随着CuO/活性炭催化剂加入量、30%H2O2氧化剂用量、反应温度的不断增加,甲基橙废水的脱色率明显增大;而增加反应时间对甲基橙废水脱色率增加幅度较小.当CuO/活性炭催化剂加入量为0.1 g、质量分数30%H2O2氧化剂加入量为6 mL、催化反应时间为2 h、催化反应温度为35℃时,其对甲基橙废水的脱色率可达到82.44%.
Based on the precursor with copper nitrate as the active component,CuO/activated carbon catalyst was prepared by impregnation roasting method,and H2O2 was used as the oxidant to compare the effect of treating simulated wastewater of methyl orange with mass concentration of 500 mg·L-1 under atmospheric pressure in the catalytic wet oxidation process.The effects of different amounts of CuO/activated carbon catalyst and 30% mass fraction of H2O2 oxidant,decolorization reaction time,and decolorization reaction temperature on the decolorization rate of methyl orange wastewater were investigated.The results showed that with the continuous increase of CuO/activated carbon catalyst dosage,30% H2O2 oxidant dosage,and reaction temperature,the decolorization rate of methyl orange wastewater significantly increased.However,increasing the reaction time had smaller effect on the decolorization rate of methyl orange wastewater.When the amount of CuO/activated carbon catalyst added was 0.1 g,the amount of 30% H2O2 oxidant added was 6 mL,the catalytic reaction time was 2 h,and the catalytic reaction temperature was 35 ℃,the decolorization rate of methyl orange wastewater could reach 82.44%.

CuO/activated carbon catalystMethyl orange wastewaterH2O2Catalytic wet air oxidation

胡伟、马凯全、秦传高

展开 >

江苏环保产业技术研究院股份公司,江苏南京 210019

黄山学院,安徽黄山 245021

浙江国际海运职业技术学院,浙江舟山 316021

CuO/活性炭催化剂 甲基橙废水 H2O2 催化湿式氧化法

江苏省科协青年科技人才托举工程项目

JSTJ-2023-XH026

2024

当代化工
中国石油抚顺石化公司,中国石化抚顺石油化工研究院,沈阳市医药和化工行业联合会

当代化工

CSTPCD
影响因子:0.412
ISSN:1671-0460
年,卷(期):2024.53(9)
  • 17