当代化工2024,Vol.53Issue(9) :2252-2257.

总磷应急去除工艺研究

Research on Emergency Removal Technology of Total Phosphorus

诸力维 刘利 彭喜林 周洋 张楷彬 刘晓 谢川 李晓林
当代化工2024,Vol.53Issue(9) :2252-2257.

总磷应急去除工艺研究

Research on Emergency Removal Technology of Total Phosphorus

诸力维 1刘利 1彭喜林 1周洋 1张楷彬 1刘晓 1谢川 1李晓林2
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作者信息

  • 1. 重庆市三峡鱼复排水有限责任公司,重庆 401133
  • 2. 西南大学化学化工学院,重庆 400715
  • 折叠

摘要

目前污水处理除磷工艺主要以厌氧-缺氧-好氧(A2/O)为主,然而A2/O工艺仅能实现正磷酸盐的去除.当非正磷酸盐浓度过高时,采取应急措施去除污水中的非正磷酸盐以确保出水水质达标是非常必要的.基于此,开展了污水中总磷的应急去除的工艺研究.通过对传统芬顿氧化、臭氧-传统芬顿氧化、次氯酸钠(NaClO)氧化等方式对比,确定了NaClO氧化为最佳氧化方式,通过进一步的探索,得出了混凝法去除正磷酸盐的最佳条件:加入10 mL质量分数为5.5%的NaClO、氧化时间为30 min、氧化搅拌转速为60 r·min-1、混凝剂体积为0.2 mL、混凝时间为20 min、搅拌速度为300 r·min-1、慢速搅拌时间10 min、慢速搅拌速度60 r·min-1、质量分数0.1%的聚丙烯酰胺体积为0.2 mL、助凝时间为30 min、助凝搅拌速度为60 r·min-1.在上述条件下,非正磷酸盐的氧化去除率最高.该实验的开展可作为A2/O工艺的重要辅助手段,当总磷浓度过高引起水质冲击时可确保出水水质达标.

Abstract

At present,the phosphorus removal in sewage treatment process is mainly based on anaerobic-anoxic-aerobic (A2/O) process.However,the A2/O process cannot achieve the removal of non-orthophosphates.Thus,emergency measures to remove non-orthophosphates in sewage are very necessary.In this experiment,the research on the emergency removal of total phosphorus in sewage was carried out.Traditional Fenton oxidation,ozone-traditional Fenton oxidation,sodium hypochlorite (NaClO) oxidation were compared.The results indicated that sodium hypochlorite oxidation was a more practical method.By exploring a series of oxidation conditions,it was concluded that when 10 mL of NaClO with mass fraction of 5.5% was added,the oxidation time was 30 min,the oxidation stirring speed was 60 r·min-1,the dosage of coagulant was 0.2 mL,and the coagulation time was 20 min,the stirring speed was 300 r·min-1,the slow stirring time was 10 min,the slow stirring speed was 60 r·min-1,the dosage of polyacrylamide with mass fraction of 0.1% was 0.2 mL,the coagulation time was 30 min,and the coagulation stirring speed was 60 r·min-1,the oxidative removal rate of non-orthophosphate was the highest.The development of this experiment can be used as an important auxiliary method of the A2/O process to ensure that the water quality of the effluent reaches the standard when the concentration of non-orthophosphate is high.

关键词

总磷/非正磷酸盐/应急处理/化学氧化/混凝法

Key words

Total phosphorus/Non-orthophosphate/Emergency treatment/Chemical oxidation/Coagulation method

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基金项目

重庆市自然科学基金面上项目(cstc2021jcyjmsxmX1182)

出版年

2024
当代化工
中国石油抚顺石化公司,中国石化抚顺石油化工研究院,沈阳市医药和化工行业联合会

当代化工

CSTPCD
影响因子:0.412
ISSN:1671-0460
参考文献量11
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