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纳米复合聚合物对水泥浆防腐性能的影响

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随着大批深井和超深井的勘探开发,高温、高压、酸性气体腐蚀等气井固井问题已经成为气田勘探开发的技术瓶颈,并且CO2 和H2S酸性气体的腐蚀对水泥石的微观结构、孔隙率、抗折强度及抗压强度都会产生影响.针对上述问题,室内研制了一种纳米复合防腐剂SPJ-2,并探究了纳米复合防腐剂SPJ-2 对水泥浆性能的影响.结果表明:该防腐剂构成的水泥浆具有良好的流变性,稠化时间可调,抗压强度大于25 MPa,稠化转化时间小于 20 min,说明水泥浆的防气窜性好.加入质量分数 3%防腐剂SPJ-2 的防腐效果比不加防腐剂的防腐效果好很多,渗透率和强度衰减下降,并且30 d腐蚀深度小于0.4 mm,满足南海油气田高温200℃固井作业条件,为该油气田后期现场作业提供了技术支撑.
The Influence of Nanocomposite Polymers on the Anti-Corrosion Performance of Cement slurry
With the exploration and development of a large number of deep and ultra deep wells,gas well cementing problems such as high temperature,high pressure,and acidic gas corrosion have become technical bottlenecks in gas field exploration and development.The corrosion of CO2 and H2S acidic gases have an impact on the microstructure,porosity,flexural strength,and compressive strength of cement stone.In response to the above issues,a nanocomposite anti-corrosion agent SPJ-2 was developed indoors,and the impact of the nanocomposite anti-corrosion agent SPJ-2 on the performance of cement slurry were investigated.The research showed that the cement slurry composed of this anti-corrosion agent had good rheological properties,adjustable thickening time,compressive strength greater than 25 MPa,and thickening conversion time less than 20 min,indicating that the cement slurry had good gas channeling resistance.The addition of 3%anti-corrosion agent SPJ-2 had much better anti-corrosion effect than the absence of anti-corrosion agent,with a decrease in permeability and strength attenuation,and a corrosion depth of less than 0.4 mm within 30 d,meeting the high temperature 200℃cementing operation conditions of oil and gas fields in South China Sea,providing technical support for the later on-site operation of the oil and gas field.

High temperatureNano polymerAnticorrosive material SPJ-2Preventing CO2 and H2S

吴杰

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中海油田服务股份有限公司油田化学事业部湛江作业公司,广东 湛江 524057

高温 纳米聚合物 防腐剂SPJ-2 防CO2和H2S

2024

当代化工
中国石油抚顺石化公司,中国石化抚顺石油化工研究院,沈阳市医药和化工行业联合会

当代化工

CSTPCD
影响因子:0.412
ISSN:1671-0460
年,卷(期):2024.53(12)