首页|柔性超疏水钙钛矿复合纸及光致发光性能

柔性超疏水钙钛矿复合纸及光致发光性能

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卤化物钙钛矿在下一代照明设备中展现出广阔的前景.然而,钙钛矿纳米晶存在柔性和水稳定性差的问题.使用羟基磷灰石(HA)纳米线作为柔性框架负载CsPbBr3 钙钛矿纳米晶,随后进行聚二甲基硅氧烷(PDMS)表面改性,制备出兼具柔性和超疏水表面的钙钛矿复合纸.所制备的 HA/CsPbBr3/PDMS 复合纸展现出卓越的柔韧性,在物理变形后可维持结构稳定.HA/CsPbBr3/PDMS 复合纸具有超疏水表面,水接触角达到151°.因此,在水中浸泡5 h后,复合纸的光致发光发射峰强度仍能保持初始值的98%,在紫外光(365 nm)照射下发射出明亮、均匀的绿色荧光.
Flexible and Superhydrophobic Perovskite Composite Paper and Its Photoluminescent Performance
The halide perovskite shows a bright prospect in the next-generation lighting devices.However,perovskite nanocrystals suffer from rigidity and poor water stability.The hydroxyapatite(HA)nanowires were used as a flexible framework to support CsPbBr3 perovskite nanocrystals,followed by polydimethylsiloxane(PDMS)modification,perovskite composite paper with flexibility and superhydrophobic surfaces was prepared.The as-fabricated HA/CsPbBr3/PDMS composite paper showed the outstanding flexibility and structural stability after physical deformation.In addition,the HA/CsPbBr3/PDMS paper possessed superhydrophobic surface with a water contact angle of 151°.Therefore,the intensity of photoluminescent emission peak kept 98%initial value even after immersing composite paper in water for 5 h,and the composite paper still displayed the strong and homogeneous green fluorescence under UV irradiation(365 nm).

SurfaceCompositesNanomaterialsSuperhydrophobicPerovskitePhotoluminescentPaper

杨霁航、戴子豪、陈飞飞

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福州大学至诚学院,福建 福州 350002

福州大学材料科学与工程学院,福建 福州 350108

表面 复合材料 纳米材料 超疏水 钙钛矿 光致发光

2024

当代化工
中国石油抚顺石化公司,中国石化抚顺石油化工研究院,沈阳市医药和化工行业联合会

当代化工

CSTPCD
影响因子:0.412
ISSN:1671-0460
年,卷(期):2024.53(12)