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含H2S环境下15CrMo钢冲刷腐蚀行为

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以珠光体组织的 15CrMo 钢为研究对象,通过高温高压反应釜模拟含 H2S、含砂环境,通过浸泡实验和电化学实验、结合腐蚀图像和元素分布分析方法对含H2S环境下15CrMo钢的冲刷腐蚀行为进行了研究.结果表明:Cr和Mo形成的致密腐蚀产物层对 15CrMo钢具有良好的保护作用,极化曲线阳极段存在明显钝化区.随后由于砂粒的冲击作用导致腐蚀产物层发生破坏,金属表面转化为活化腐蚀;同时腐蚀电位基本保持不变,说明主要以点蚀特征为主,但没有出现典型的沟槽状冲刷腐蚀特征.此外,在H2S和冲刷的共同作用下,15CrMo钢表面形成微裂纹.
Erosion-Corrosion Behavior of 15CrMo Steel in H2S Environment
15CrMo steel with pearlitic structure was taken as the research object,and the environment containing H2S and sand was simulated and established by high temperature-pressure reactor,in which the erosion corrosion behavior of 15CrMo steel in the environment containing H2S was studied by immersion experiment and electrochemical experiment,combined with corrosion image and element distribution analysis method.The results showed that the dense corrosion product layer formed by Cr and Mo had a good protective effect on 15CrMo steel,and there was an obvious passivation zone in the anode section of the polarization curve.Subsequently,the impact of sand particles led to the destruction of the corrosion product layer,and the metal surface was transformed into active corrosion.At the same time,the corrosion potential remained basically unchanged,indicating that pitting corrosion was the main feature,but there was no typical trench erosion corrosion feature.In addition,under the combined action of H2S and scouring,micro-cracks were formed on the surface of 15CrMo steel.

H2S-containing environment15CrMo steelGas-liquid-solid flowErosionCorrosion morphologyPolarization curveCorrosion potentialCorrosion current density

刘波、邵珠峰、赵勇、王志芹、杨超、刘建国

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山东瑞康安全评价有限公司,山东 日照 276800

中国石化胜利油田分公司技术检测中心,山东 东营 257000

中国石油大学(华东),山东 青岛 266580

H2S环境 15CrMo钢 气液固多相流 冲刷腐蚀 腐蚀图像 极化曲线 腐蚀电位 腐蚀电流密度

2024

当代化工
中国石油抚顺石化公司,中国石化抚顺石油化工研究院,沈阳市医药和化工行业联合会

当代化工

CSTPCD
影响因子:0.412
ISSN:1671-0460
年,卷(期):2024.53(12)