首页|环保型纳米吸收剂材料对工业废水污染物去除性能评价

环保型纳米吸收剂材料对工业废水污染物去除性能评价

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通过制备纳米氧化镁对工业废水中氟的吸附性能进行研究.用傅里叶变换红外光谱、能量色散分析对纯纳米氧化镁和吸附了氟的纳米氧化镁进行了表征.结果表明:该吸附剂的比表面积为92.46 m2·g-1,当纳米氧化镁的投加量为0.6 g·L-1 时,除氟效果最好(90%).纳米氧化镁对氟的吸附对pH变化不太敏感.吸附氟离子主要受羟基离子存在影响.其他离子的存在对纳米氧化镁的氟吸附容量没有显著影响.Freundlich 模型比Langmuir 模型更好地描述了吸附过程中的准二级动力学过程.再生研究结果表明:1.0 mol·L-1 的洗脱剂对氟离子的脱附率为95.0%,其次是NaOH(2.0 mol·L-1),再生率为25.0%.
Evaluation of Removal Performance of Environmentally Friendly Nanoabsorbent Materials for Industrial Wastewater Pollutants
The adsorption performance of fluorine in industrial wastewater was studied by preparing nano-magnesium oxide.The pure nano-MgO and nano-MgO adsorbed with fluorine were characterized by Fourier transform infrared spectroscopy and energy dispersion analysis.The results showed that the specific surface area of the adsorbent was 92.46 m2·g-1,and the best fluorine removal effect(90%)was achieved when the dosage of nanomagnesium oxide was 0.6 g·L-1.The adsorption of fluorine by nano-magnesium oxide was less sensitive to pH changes.Adsorption of fluoride ions was mainly affected by the presence of hydroxyl ions.The presence of other ions was found to have no significant effect on the fluorine adsorption capacity of magnesium oxide nanoparticles.The Freundlich model described the quasi-secondary kinetic processes during adsorption better than the Langmuir model.Regeneration test results showed that 1.0 mol·L-1 eluent desorbed 95.0%of fluoride ions,followed by NaOH(2.0 mol·L-1)with 25.0%regeneration rate.

Wastewater treatmentDefluoridationAdsorptionEnvironmental protectionNanomaterialsAbsorbents

徐云龙、蔡志军、许国栋

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苏州中晟环境修复有限公司,江苏 苏州 215000

污水处理 除氟 吸附性 环保 纳米材料 吸收剂

2024

当代化工
中国石油抚顺石化公司,中国石化抚顺石油化工研究院,沈阳市医药和化工行业联合会

当代化工

CSTPCD
影响因子:0.412
ISSN:1671-0460
年,卷(期):2024.53(12)