首页|基于Aspen plus的典型林业生物质气化制氢过程模拟研究

基于Aspen plus的典型林业生物质气化制氢过程模拟研究

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林业生物质作为一种独特的碳基可再生能源资源,其气化制氢技术的开发对于我国减少对化石能源的依赖、强化能源安全以及推进碳达峰与碳中和目标的实现非常重要.鉴于生物质气化制氢技术路径的多样性,基于热力学原理的深入评估与工艺优化显得尤为重要,旨在实现林业生物质资源的高效转化与低成本绿色氢能的制备.本研究以典型林业生物质——松木屑作为原料,运用Aspen plus软件平台,构建了变压吸附生物质气化制氢系统模型.在气化工艺中,采用控制变量法,系统地探讨了氧当量比、气化温度及水气比等关键参数对氢气产量、热蒸汽生成量及系统电耗的综合影响.文章通过数据分析与比较,确定了气化温度850℃、氧当量比 0.30、水气比 0.1 为本研究最优工况.燃气组分中氢气含量高达27.21%,伴随生成一氧化碳(33.15%)、二氧化碳(20.97%)、水蒸气(18.60%)、氮气(0.06%)及微量甲烷.变压吸附工艺产生的氢气体积数较大,为 94.36 m3/h,且氢气较为纯净,但整个系统消耗电量相对较高,为42.57 kW·h.综上所述,本研究可以为林业生物质气化制氢技术的工艺优化提供数据支持与理论依据.
Process simulation study on typical forest biomass gasification for hydrogen production based on Aspen plus
Forest biomass as a unique renewable carbon energy resource,its development of forest biomass gasification for hydrogen production is particularly important for China to reduce its dependence on fossil fuels,enhance energy se-curity,and achieve carbon peaking and neutrality goals.Given the diverse pathways of biomass gasification for hydro-gen production,a thorough evaluation and process optimization based on thermodynamic principles are particularly im-portant to achieve efficient conversion of forest biomass resources and low-cost production of green hydrogen.This study chosed sawdust as raw material,and utilized the Aspen plus software platform to construct a model of a variable pres-sure adsorption biomass gasification hydrogen production system.By using a control variable method in the gasification process,the study systematically investigated the comprehensive impact of key parameters such as oxygen equivalence ratio,gasification temperature,and steam-gas ratio on hydrogen production,heat steam generation,and system power consumption.Through detailed data analysis and comparison,it was determined that under the optimized conditions of a gasification temperature of 850℃,oxygen equivalence ratio of 0.3,and steam-to-gas ratio of 0.1,the process could achieve optimal performance.At this point,the hydrogen content in the gas composition was as high as 27.21%,ac-companied by carbon monoxide(33.15%),carbon dioxide(20.97%),steam(18.60%),nitrogen(0.06%),and trace amounts of methane.The variable pressure adsorption process generated a large volume of hydrogen gas,reaching 94.36 m3/h,with relatively high purity,but the entire system consumed a relatively high amount of electricity,at 42.57 kW·h.In conclusion,this study provides detailed data support and theoretical basis for process optimization of forest biomass gasification for hydrogen production.

forest biomassgasificationsimulationAspen plus software platformhydrogen production

高亚丽、田丽娜、崔东旭、宋旭东、于广锁、王辅臣、李斌、卫俊涛

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南京林业大学 材料科学与工程学院,江苏省林业生物质材料与能源国际合作联合实验室,江苏 南京 210037

宁夏大学 化学化工学院,省部共建煤炭高效利用与绿色化工国家重点实验室,宁夏 银川 750021

华东理工大学 资源与环境工程学院,大型煤气化及煤基新材料国家工程研究中心(上海),上海 200237

安徽农业大学 工学院,安徽 合肥 230031

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林业生物质 气化 模拟 Aspen plus软件平台 制氢

国家自然科学基金江苏省高等学校自然科学研究项目江苏省研究生科研与实践创新计划

2220816422KJB470017KYCX24_1298

2024

新能源科技
江苏省轻工科技情报总站 中国自行车协会助力自行车专业委员会

新能源科技

影响因子:0.022
ISSN:2096-8809
年,卷(期):2024.5(4)