首页|早子沟金矿黄铁矿原位微量元素和硫同位素特征对矿床成因的指示

早子沟金矿黄铁矿原位微量元素和硫同位素特征对矿床成因的指示

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早子沟金矿是西秦岭造山带的一个代表性金矿床,其成矿物质来源和矿床类型存在较大争议.对该矿床不同类型的黄铁矿进行了详细的显微结构观察,并开展了LA-ICP-MS原位微量元素和硫同位素分析,以探讨成矿物质来源,深化对矿床成因的认识.黄铁矿至少可以分为3个世代(Py1、Py2和Py3),其中Py2和Py3为主要的载金矿物.Py1具有高Pb与低Ag、Au、W、Tl的特点,δ34S值为-7.4‰~-5.8‰;Py2的Au、As、Ag、W含量较高,Tl含量较低,δ34S值为-16.6‰~-4.2‰,Au主要以固溶体金(Au+)的形式存在;Py3具有高Sb、Tl与低W、Bi的特征,δ34S值为-25.2‰~-20.1‰.Au以固溶体金、纳米粒子金的形式存在.研究结果表明,早子沟金矿金的沉淀富集可能与水-岩反应以及流体沸腾作用相关,早子沟金矿应该属于造山型金矿床.
In Situ Trace Elements and Sulfur Isotope Analysis of Pyrite from Zaozigou Gold Deposit:Implications for Ore Genesis
Zaozigou is a representative gold deposit in West Qinling orogenic belt.The source of ore-forming materials and the genetic type of the deposit are still in debate.The microstructure,trace elements and sulfur isotopes of gold-bearing pyrite were analyzed by LA-ICP-MS to constrain the source of ore-forming materials and ore genesis.Pyrite can be divided into at least three generations(Py1,Py2 and Py3),of which Py2 and Py3 are the main gold-bearing minerals.Py1 is characterized by high Pb and low Ag,Au,W,and Tl contents.The δ34S values of Py1 range from-7.4‰ to-5.8‰.The Au,As,Ag,and W contents of Py2 are relatively high,while the Tl content is relatively low.The δ34S values of Py2 range from-16.6‰ to-4.2 ‰,and Au mainly exists in the form of solid solution(Au+).Py3 has high contents of Sb and Tl,and low contents of W and Bi.The δ34S values of Py3 vary from-25.2‰ to-20.1‰.The gold occurs as structurally bound gold and nanoparticles.The study indicates that the precipitation and enrichment of gold in the Zaozigou gold deposit may be related to water-rock interactions and fluid boiling.The Zaozigou gold deposit should be classified as an orogenic type gold deposit.

pyrite texturetrace elementsulfur isotopeZaozigou gold depositore deposit

董子良、胡新露

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中国地质科学院,北京 100037

中国地质大学资源学院,湖北武汉 430074

黄铁矿结构 微量元素 S同位素 早子沟金矿 矿床学

2024

地球科学
中国地质大学

地球科学

CSTPCD北大核心
影响因子:1.447
ISSN:1000-2383
年,卷(期):2024.49(12)