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黄土高原全新世土壤碳酸盐团簇同位素的温度重建

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黄土高原黄土-古土壤序列中保存有丰富的土壤碳酸盐,是利用碳酸盐团簇同位素(Δ47)定量重建古温度的重要地质载体之一.然而,黄土高原全新世土壤碳酸盐Δ47及其气候指示意义的系统研究仍然缺乏.本研究分析了黄土高原南缘渭南剖面和中部洛川剖面上部3 m沉积中保存的全新世土壤碳酸盐(钙结核)的团簇同位素组成,监测了现在地形条件下距地表4m以内不同深度的土壤温度.结果显示,Δ47定量重建的全新世土壤碳酸盐团簇同位素温度(T47)与现代暖季节温度相近,渭南剖面T47平均值约为25℃,洛川剖面约为18℃,较区域年均温高8~10℃.根据T47和土壤碳酸盐氧同位素组成(δ18O)重建的土壤水δ18O也与暖季节降水的δ18O基本一致,这些数据表明黄土高原土壤碳酸盐记录了暖季节的环境信息.值得注意的是,渭南和洛川剖面钙结核T47值与其形成深度的土壤温度基本吻合,结合前人研究结果,这暗示了土壤碳酸盐形成深度对其T47具有显著影响.因此,在将来土壤碳酸盐Δ47的研究中,评估土壤碳酸盐形成深度至关重要.
TEMPERATURE RECONSTRUCTION USING THE CLUMPED ISOTOPE FOR THE HOLOCENE SOIL CARBONATES ON THE CHINESE LOESS PLATEAU
Abundant soil carbonates are preserved in the loess-paleosol sequences,which are invaluable archive for the carbonate clumped isotope(Δ47)analysis to quantitatively reconstruct paleotemperature and environmental changes.However,no systematic studies were conducted to investigate the Δ47 compositions of the Holocene soil carbonates and their climatic implications on the Chinese Loess Plateau(CLP).Thus,this study analyzed the stable and clumped isotopes of the Holocene soil carbonates obtained from the upper 3 meters in Weinan(34.5°N,109.6°E)and Luochuan(35.7°N,109.4° E)sections,which are located on the southern and middle part of the CLP,respectively.Meanwhile,the soil temperature was monitored at different depths(0.5 m,1 m,2 m and 4 m)for the upper 4 meters.The results show that the soil carbonate formation temperature(T47)reconstructed from Δ47 values is approaching warm season temperature,and the mean T47 is 25 ℃ for Weinan and 18℃ for Luochuan,which are 8~10℃ higher than mean annual temperature in the studied region.Furthermore,the soil water oxygen isotope compositions(δ18O)were reconstructed from T47 and soil carbonate δ18O,which are consistent with the monitored warm season precipitation δ18O.Altogether,these data suggest that the soil carbonates were precipitated during the warm-wet season on the CLP.Notably,the T47 in the two sections are similar with the measured soil temperatures at the soil carbonates formation depths.This indicates the important role of the carbonate's formation depth,because the T47 of soil carbonates reflected the soil temperature which is further strongly related to the soil depth.In other word,the deeper formation depth of soil carbonates will correspond to lower/mean annual temperature.This inference is supported by the recent study on the Lingtai section in central part of CLP,which show that the mean T47 of the soil carbonates formed in the last interglacial is 5℃ lower than those for the Holocene.Besides,the published results also imply the influences of formation depth of soil carbonates on their carbon and oxygen isotopes.Therefore,it is pivotal to constraint the formation depth of soil carbonates as well as their formation season in future studies.

soil carbonateclumped isotope(Δ47)HoloceneChinese Loess Plateauseasonality

董吉宝、John EILER

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中国科学院地球环境研究所,黄土与第四纪地质国家重点实验室,陕西西安 710061

California Institute of Technology,Pasadena,CA 91125,USA

土壤碳酸盐 团簇同位素(Δ47) 全新世 黄土高原 季节性

中国科学院青年创新促进会项目

2021412

2024

第四纪研究
中国科学院地质与地球物理研究所 中国第四纪研究委员会

第四纪研究

CSTPCD北大核心
影响因子:2.939
ISSN:1001-7410
年,卷(期):2024.44(5)