大学化学2024,Vol.39Issue(1) :359-363.DOI:10.3866/PKU.DXHX202307025

在重力场中的热力学基本方程及应用

Basic Thermodynamic Equations in the Gravitational Field and Their Applications

李淑颖 孙文东
大学化学2024,Vol.39Issue(1) :359-363.DOI:10.3866/PKU.DXHX202307025

在重力场中的热力学基本方程及应用

Basic Thermodynamic Equations in the Gravitational Field and Their Applications

李淑颖 1孙文东1
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作者信息

  • 1. 东北师范大学化学学院,长春 130024
  • 折叠

摘要

通过引入组分B的摩尔重力势能,导出了在重力场中多组分系统的热力学基本方程.定义了重力化学势,据此判断变化的方向和限度.最后列举了重力化学势判据的应用实例:理想气体压力随高度分布公式,溶胶粒子在介质中沉降平衡公式.

Abstract

Through the introduction of the molar gravitational potential energy for component B,we derive the fundamental thermodynamic equations for a multi-component system in a gravitational field.The gravitational chemical potential is defined,allowing for the determination of the direction and extent of changes.Concluding,we provide application examples of the criteria based on the gravitational chemical potential:the pressure distribution formula for an ideal gas as a function of altitude,and the sedimentation equilibrium formula for sol particles in a medium.

关键词

重力场/热力学基本方程/重力化学势/摩尔重力势能

Key words

Gravitational field/Basic equation of thermodynamics/Gravitational chemical potential/Molar gravitational potential energy

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出版年

2024
大学化学
北京大学 中国化学会

大学化学

影响因子:0.636
ISSN:1000-8438
参考文献量6
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