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在重力场中的热力学基本方程及应用

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通过引入组分B的摩尔重力势能,导出了在重力场中多组分系统的热力学基本方程.定义了重力化学势,据此判断变化的方向和限度.最后列举了重力化学势判据的应用实例:理想气体压力随高度分布公式,溶胶粒子在介质中沉降平衡公式.
Basic Thermodynamic Equations in the Gravitational Field and Their Applications
Through the introduction of the molar gravitational potential energy for component B,we derive the fundamental thermodynamic equations for a multi-component system in a gravitational field.The gravitational chemical potential is defined,allowing for the determination of the direction and extent of changes.Concluding,we provide application examples of the criteria based on the gravitational chemical potential:the pressure distribution formula for an ideal gas as a function of altitude,and the sedimentation equilibrium formula for sol particles in a medium.

Gravitational fieldBasic equation of thermodynamicsGravitational chemical potentialMolar gravitational potential energy

李淑颖、孙文东

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东北师范大学化学学院,长春 130024

重力场 热力学基本方程 重力化学势 摩尔重力势能

2024

大学化学
北京大学 中国化学会

大学化学

影响因子:0.636
ISSN:1000-8438
年,卷(期):2024.39(1)
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