二茂铁苯基衍生物的综合化学实验设计
Comprehensive Chemistry Experimental Design of Ferrocenylphenyl Derivatives
鄢剑锋 1肖雅婷 1左鑫 1林彩霞 1袁耀锋1
作者信息
摘要
介绍了一个综合化学实验,涉及二茂铁苯基衍生物的合成、光物理和电化学性质的表征.该实验难度适中,综合运用了多种表征方法和测试手段,将大学基础化学理论、基本实验技能与金属有机领域的学术研究相结合.采用逆合成分析法设计了"一锅法"水相合成路线,旨在帮助学生树立绿色化学的概念以及培养可持续发展的思想.实验运用了紫外-可见吸收光谱和电化学方法对目标化合物的光物理和电化学性质进行研究,并结合量化计算手段详细比较了给电子基团和吸电子基团对分子电荷分布带来的影响.通过以科研反哺教学的模式,本实验不仅使学生掌握了基本的科研训练,而且培养了他们的综合实验素质.
Abstract
This article presents a comprehensive chemistry experiment that involves the synthesis,photophysical and electrochemical characterization of ferrocenylphenyl derivatives.By integrating multiple characterization methods and test approaches,this experiment helps students learn fundamental college chemistry theory,basic laboratory skills,and academic research in the field of organometallics.UV-Visible spectroscopic and electrochemical methods were utilized to study the target compounds and compare the electron-donating and electron-withdrawing effects on the molecular spectrum via a quantitative computation methodology.Furthermore,it stimulates the creation of green chemistry values and sustainable development mindfulness while developing students'scientific research and comprehensive experimental skills.
关键词
二茂铁苯基衍生物/水相合成/光物理/电化学/量化计算/综合化学实验Key words
Ferrocenylphenyl derivatives/Aqueous synthesis/Photophysical/Electrochemistry/Quantum chemical calculation/Comprehensive chemistry experiment引用本文复制引用
基金项目
国家自然科学基金(22071025)
教育部基础学科拔尖计划2.0研究课题(2022)(20222114)
福建省中青年教师教育科研项目(科技类)(JAT210020)
出版年
2024
国家科技期刊平台
NSTL
万方数据