可见光诱导大茴香醛的高效合成
Efficient Synthesis of Anethaldehyde Induced by Visible Light
李杰 1钱汇达 1潘德阳 1王雯婧 1朱大亮 1房忠雪1
作者信息
- 1. 盐城师范学院化学与环境工程学院,江苏 盐城 224007
- 折叠
摘要
4-甲氧基苯甲醛,俗名大茴香醛,广泛应用于药物合成和香水调配等领域.但是传统合成大茴香醛的工艺缺点,导致其合成途径很难适合本科实验教学.本实验在温和且无金属的条件下,通过可见光诱导4-甲氧基苯甲醇来制备大茴香醛,这不仅提供了醇氧化、醛制备的新方法,而且也向学生拓展了光化学和自由基化学等重要知识,为培养具有科研思维和创新能力的新工科人才提供支撑.
Abstract
Anisaldehyde,also known as p-anisaldehyde,is widely used in the synthesis of pharmaceuticals and perfume formulation.However,the drawbacks of traditional methods for synthesizing anisaldehyde make it challenging to adapt them for undergraduate laboratory teaching.This experiment presents a novel approach to preparing anisaldehyde by mild and metal-free conditions,utilizing visible light-induced oxidation of p-anisyl alcohol.This not only offers a new method for alcohol oxidation and aldehyde preparation but also expands students'knowledge in the fields of photochemistry and radical chemistry,which provides a support for cultivating new engineering talents with scientific research thinking and innovation capacity.
关键词
可见光诱导/醇氧化/无金属/大茴香醛Key words
Visible-light-induced/Oxidation of alcohol/Metal-free/Anisaldehyde引用本文复制引用
基金项目
江苏省教育厅面上项目(22KJB150048)
出版年
2024
国家科技期刊平台
NSTL
万方数据