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己内酰胺环状低聚物轶事——"环公主"的百变人生

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在己内酰胺水解开环制备聚酰胺6的过程中会产生大量环状低聚物,其中环状二聚体易团聚,影响工艺安全和产品性能.因此了解环状低聚物的相关特性对保证生产工艺安全和提升产品品质十分重要.本文采用拟人的手法,生动形象地介绍了环状低聚物的特性,科普了环状二聚体的形成机制、晶型转变行为和危害,提出了工艺优化的方法.
The Tale of Caprolactam Cyclic Oligomers:The Ever-changing Life of"Princess Cyclo"
During the hydrolysis process of caprolactam to produce polyamide 6,a considerable number of cyclic oligomers are inevitably formed.Among these,the cyclic dimer,with its propensity for aggregation,poses significant challenges to both process safety and product quality.Thus,understanding the characteristics of cyclic oligomers is crucial for ensuring process safety and enhancing product quality.This paper employs a personification approach to vividly describe the properties of cyclic oligomers,elucidating the formation mechanism of cyclic dimers,delineating the behavior of crystal phase transitions,and highlighting the detrimental effects of cyclic dimers on industrial production.Moreover,it proposes methods for process optimization.

Caprolactam cyclic oligomerCyclic dimerCrystal phase transformationPerformanceIndustrial impact

郑红、彭馨、易春旺

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湖南师范大学化学化工学院,长沙 410000

己内酰胺环状低聚物 环状二聚体 晶型转变 性能 工业影响

湖南省教改项目

HNJG-2022-0553

2024

大学化学
北京大学 中国化学会

大学化学

影响因子:0.636
ISSN:1000-8438
年,卷(期):2024.39(9)
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