首页|沉淀滴定终点误差的计算公式及应用——以莫尔法为例

沉淀滴定终点误差的计算公式及应用——以莫尔法为例

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终点误差是分析化学中的重要教学内容.基于沉淀溶解平衡理论和终点误差定义,推导出了计算莫尔法终点误差的一般公式.介绍了该公式在直接计算终点误差、确定滴定突跃范围及确定指示剂的最低需要量等方面的应用,所得计算结果均与文献值相符.该公式的构建进一步完善了计算终点误差的新方法体系,将有力推动分析化学一流课程的建设.
The Construction and Application of the Calculation Formula for Endpoint Error in Precipitation Titration:A Case Study of the Mohr Method
Endpoint error is an important topic in analytical chemistry education.Based on the theory of precipitation-dissolution equilibrium and the definition of endpoint error,a general formula for calculating the endpoint error in the Mohr method has been derived.The application of this formula in directly calculating the endpoint error,determining the titration jump range,and determining the minimum required amount of indicator is introduced,and the calculated results are consistent with the literature values.The construction of this formula further improves the new methodological system for calculating endpoint errors,which will effectively promote the development of first-class courses in analytical chemistry.

Precipitation titrationEndpoint errorTitration jumpIndicator

苏铁军

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荆州学院健康医学院,湖北 荆州 434020

教育部分析化学课程虚拟教研室,长沙 410082

沉淀滴定 终点误差 滴定突跃 指示剂

2024

大学化学
北京大学 中国化学会

大学化学

影响因子:0.636
ISSN:1000-8438
年,卷(期):2024.39(11)