首页|d带中心理论探究MoS2电催化氢气析出反应机理的发展

d带中心理论探究MoS2电催化氢气析出反应机理的发展

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二硫化钼(MoS2)纳米片是一种典型的二维材料,因其独特可调的电子结构和优异的氢气析出反应(HER)电催化活性受到研究者的广泛关注.为了进一步提高其电催化性能,科学家深入研究反应的微观机理,以期阐明材料电子结构中影响电催化性能的关键因素,构建合理的电子描述符.本文综述了近年来d带中心理论探究MoS2电催化HER机理的起源、发展和现状,以期为该类催化剂的进一步发展提供指导.
A review of the development of d-band center theory to study the mechanism of MoS2 electrocatalytic hydrogen reaction
Molybdenum disulfide(MoS2)nanosheets,a typical two-dimensional material,have received much attention for its unique tunable electronic structure and excellent electrocatalytic activity for hydrogen evolution reac-tion(HER).In order to further improve its electrocatalytic performance,in-depth investigations on microscopic HER mechanism have been conducted to elucidate the key factors influencing the electrocatalytic performance with-in the material's electronic structure and construct reasonable electronic descriptors.This paper reviews the origin,development and current status of the d-band center theory to probe the mechanism of MoS2 electrocatalytic HER in recent years,with a view to providing guidance for the further development of this type of catalyst.

MoS2 nanosheetsHERelectrocatalysiselectronic descriptorsd-band center theory

刘世平、黄晓晓

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北京师范大学物理学系,北京 100875

MoS2纳米片 HER 电催化 电子描述符 d带中心理论

中央高校基本科研业务费专项

2024

大学物理
中国物理学会

大学物理

影响因子:0.333
ISSN:1000-0712
年,卷(期):2024.43(2)
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