地质论评2025,Vol.71Issue(1) :317-327.DOI:10.16509/j.georeview.2024.07.045

四川彭州大宝山铜矿矿石与三星堆青铜器关联性研究

Research on the correlation between the ore from Dabaoshan copper deposit in Pengzhou,Sichuan,and Sanxingdui Bronze Ware

刘建成 王运生 唐涛 谢振斌 井浩 詹明斌 唐之茗 肖礼颖
地质论评2025,Vol.71Issue(1) :317-327.DOI:10.16509/j.georeview.2024.07.045

四川彭州大宝山铜矿矿石与三星堆青铜器关联性研究

Research on the correlation between the ore from Dabaoshan copper deposit in Pengzhou,Sichuan,and Sanxingdui Bronze Ware

刘建成 1王运生 2唐涛 2谢振斌 1井浩 3詹明斌 2唐之茗 2肖礼颖4
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作者信息

  • 1. 四川省文物考古研究院,成都,610041
  • 2. 成都理工大学地质灾害防治与地质环境保护国家重点实验室,成都,610059
  • 3. 青海交通职业技术学院,西宁,810003
  • 4. 彭州市文物保护管理所,成都,611930
  • 折叠

摘要

四川广汉三星堆遗址出土了大量青铜器,目前关于三星堆青铜器铜料来源的研究尚无定论,通过对大宝山铜矿遗留矿洞进行实际调查,并在不同采矿点采集矿石以及冶炼弃渣样品进行铅同位素测定以及Cu、Pb、Zn等主要金属元素,Au、Ag、Se、As、Sb等亲铜元素和Ni、Co等亲铁元素的含量测定.采用铅同位素比值法和微量元素示踪法,与前人对三星堆青铜器化学成分的研究结果进行比对,综合分析大宝山铜矿与三星堆青铜器铜料来源的关联性,结果揭示:①大宝山铜矿石为普通铅,用铅同位素比值法对三星堆这类含特殊铅青铜器的铜料进行溯源研究不能准确得到其铜矿石来源.②微量元素含量特征表明三星堆大部分青铜器的微量元素组合特征与大宝山铜矿的微量元素特征接近.③通过微量元素的进一步因子分析和聚类分析,表明三星堆部分青铜器的微量元素组合特征与大宝山铜矿大部分样品相似,该部分青铜器铜料很可能来自大宝山铜矿.

Abstract

A large number of bronze wares have been unearthed from the Sanxingdui site in Guanghan,Sichuan Province.Currently,there is no consensus on the source of copper used in the Sanxingdui bronze wares.Through actual investigations of abandoned mines in the Dabaoshan Copper Deposit,samples of ores and smelting slags were collected from different mining sites for lead isotope determination and the measurement of Cu,Pb,Zn,and other major metallic elements,as well as copper-philic elements such as Au,Ag,Se,As,Sb,and iron-philic elements like Ni,Co.By utilizing the lead isotope ratio method and trace element tracing method,and comparing with previous research results on the chemical composition of Sanxingdui bronze wares,this study comprehensively analyzes the correlation between the copper sources of Dabaoshan Copper Deposit and Sanxingdui bronze wares.The results reveal the following:① The copper ores from Dabaoshan are ordinary lead,and using the lead isotope ratio method to trace the copper source of Sanxingdui bronze wares containing special lead cannot accurately determine their copper ore origins.② The trace element content characteristics indicate that the trace element combination features of most of the Sanxingdui bronze wares are similar to those of the Dabaoshan Copper Deposit.③ Further factor analysis and cluster analysis of trace elements show that the trace element combination characteristics of some Sanxingdui bronze wares are similar to those of most samples from the Dabaoshan Copper Deposit,suggesting that the copper material for these bronze wares likely originated from the Dabaoshan Copper Deposit.

关键词

大宝山铜矿/三星堆青铜器/铅同位素/微量元素示踪法

Key words

Dabaoshan copper deposit/Sanxingdui Bronze Ware/lead isotope/trace element tracing method

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出版年

2025
地质论评
中国地质学会

地质论评

北大核心
影响因子:1.842
ISSN:0371-5736
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