首页|黔中地区蔡家坝铝土矿床富锂铝土岩地球化学特征及沉积环境研究

黔中地区蔡家坝铝土矿床富锂铝土岩地球化学特征及沉积环境研究

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贵州清镇蔡家坝铝土矿床是近年来在黔中铝土矿成矿区内新发现的铝土矿床之一,铝土矿体呈层状及似层状产于下石炭统九架炉组地层中.本研究通过对蔡家坝铝土矿床中以铝土岩为主的含铝岩系钻孔岩心剖面开展详细的矿物学和地球化学研究,发现含铝岩系中的铝土岩明显具有Li超富集的现象.研究结果表明,含铝岩系的所有样品中均富含高浓度的Li(210~2480)×10-6;其中,10件铝土岩的Li含量为(210~2480)×10-6(平均1198.9×10-6),3件铝土矿石的Li含量为(412~1440)×10-6(平均980.7×10-6),表现出明显超富集的特征.光学显微镜和XRD分析显示,富锂铝土岩主要由伊利石、高岭石和绿泥石组成,以及少量的硬水铝石、勃姆石、黄铁矿、锐钛矿等.结合矿物学和地球化学证据,研究区铝土岩中的Li主要赋存在高岭石和伊利石等粘土矿物中,当铝土岩中Al2O3含量介于30%~40%之间以及Al2O3/SiO2比值介于1~1.5时,铝土岩中的Li最为富集.元素地球化学分析表明,研究区内的富锂铝土岩形成于温暖潮湿和相对氧化的陆相淡水环境.
Geochemical Characteristics and Sedimentary Environment of Li-Rich Bauxite in the Caijiaba Bauxite Deposit,Central Guizhou Province
The Caijiaba bauxite deposit in Qingzhen,Guizhou is one of the newly discovered bauxite deposits in the central Guizhou bauxite deposit area in recent years. The bauxite deposits were layered and quasi layered,and occurred in the Lower Carboniferous Jiujialu Formation. This study conducted detailed mineralogical and geochemical studies on the core profiles of aluminum bearing rock series in the Caijiaba bauxite deposit. The aluminum bearing rock series in the Caijiaba bauxite deposit exhibits obvious Li hyperaccumulation. The research results indicate that all samples of aluminum bearing rock series contain high concentrations of Li (210~2480) ×10-6. Among them,ten pieces of bauxite rock have Li content of (210~2480)×10-6 (average 1198.9×10-6),and three bauxite ores contain Li content (412~1440)×10-6 (average 980.7×10-6),showing obvious super enrichment characteristics. Optical microscopy and XRD analysis show that the lithium rich bauxite rock was mainly composed of illite,kaolinite,and chlorite,as well as a small amount of hard alumina,boehmite,pyrite,and rutile. Based on mineralogical and geochemical evidence,Li was mainly present in clay minerals such as kaolinite and illite in the study area. When the Al2O3 content in bauxite ranges from 30% to 40% and the Al2O3/SiO2 ratio ranges from 1 to 1.5,Li was most enriched in bauxite. Element geochemical analysis shows that the lithium rich bauxite rocks in the study area were formed in a warm,humid,and relatively oxidized terrestrial freshwater environment.

bauxiteLi-rich bauxite rockJiujialu Formationoccurrence statesedimentary environmentCaijiabacentral Guizhou Province

朱尤青、罗朝坤、杨晓飞、刘江

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贵州省有色金属和核工业地质勘查局一总队,贵州贵阳 551400

贵州大学资源与环境工程学院 贵州贵阳 550025

铝土矿 富锂铝土岩 九架炉组 赋存状态 沉积环境 蔡家坝 黔中地区

贵州省重点矿产资源大精查专项资金项目

MCHC-ZC20212218-2

2024

地质与勘探
中国冶金地质总局矿产资源研究院 中国地质学会

地质与勘探

CSTPCD北大核心
影响因子:1.853
ISSN:0495-5331
年,卷(期):2024.60(4)
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