首页|用于全氟辛烷磺酸盐检测的"开启"式荧光探针

用于全氟辛烷磺酸盐检测的"开启"式荧光探针

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全氟辛烷磺酸盐(Perfluorooctane sulfonate,PFOS)是一种持久有机污染物,具有生物毒性、高稳定性、存在范围广的特点,严重威胁人类健康安全.因此,对PFOS的检测具有重要意义.本文通过简单的合成制备了一种四苯基乙烯衍生物(TPE-py)用于检测PFOS.通过核磁共振谱图、荧光光谱以及紫外-可见吸收光谱等方法对其分子结构、光物理性质、检测效果和传感机理进行了研究.实验结果表明,基于静电相互作用和聚集诱导发光性质,TPE-py可实现对PFOS"开启"式的快速定量检测,检测限为0.11 μmol/L.
A"Turn-On"Fluorescent Probe for Detection of Perfluorooctane Sulfonate
Perfluorooctane sulfonate(PFOS)is a persistent organic pollutant,which has the characteristics of bio-toxicity,high stability and wide distribution,which is a great threat to human health and safety.Therefore,the de-tection of PFOS is of great significance.In this paper,a tetraphenylvinyl derivative fluorescent probe(TPE-py)was prepared by simple synthesis for the detection of PFOS.The molecular structure,photophysical property,detection effect and sensing mechanism were studied by means of NMR spectroscopy,fluorescence spectrum and ultraviolet-visible absorption spectrum.The results show that TPE-py was successfully prepared and it can detect PFOS quickly and quantitatively based on the properties of electrostatic interaction and aggregation-induced emission by turn-on mode and the detection limit is 0.11 μmol/L.

tetraphenylethyleneaggregation-induced emissionperfluorooctane sulfonate

宋学智、宋一凡、WONG Shiqing、张燕宁、刘俊杰、王婕、王丽娜、任相魁

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天津大学化工学院 天津市膜科学与海水淡化技术重点实验室,天津 300350

天津大学 浙江研究院,浙江 宁波 315201

河北师范大学 生命科学学院,河北 石家庄 050024

四苯基乙烯 聚集诱导发光 全氟辛烷磺酸盐

国家自然科学基金国家自然科学基金中国教育国际交流协会中国-中东欧国家高校联合教育项目

22175129218751572021102

2024

发光学报
中国物理学会发光分会,中国科学院长春光学精密机械与物理研究所

发光学报

CSTPCD北大核心
影响因子:1.301
ISSN:1000-7032
年,卷(期):2024.45(5)