发光学报2024,Vol.45Issue(9) :1456-1466.DOI:10.37188/CJL.20240137

反常热猝灭Sr2Ga2SiO7∶Sm3+红色荧光粉的合成及发光性能

Synthesis and Luminescence Properties of Abnormal Thermal Quenching Red Phosphor Sr2Ga2SiO7:Sm3+

李婧 许英朝 洪俊煌 刘月 张贤玉
发光学报2024,Vol.45Issue(9) :1456-1466.DOI:10.37188/CJL.20240137

反常热猝灭Sr2Ga2SiO7∶Sm3+红色荧光粉的合成及发光性能

Synthesis and Luminescence Properties of Abnormal Thermal Quenching Red Phosphor Sr2Ga2SiO7:Sm3+

李婧 1许英朝 2洪俊煌 1刘月 1张贤玉1
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作者信息

  • 1. 厦门理工学院 光电与通信工程学院,福建 厦门 361024
  • 2. 厦门理工学院 光电与通信工程学院,福建 厦门 361024;厦门理工学院 福建省光电技术与器件重点实验室,福建 厦门 361024
  • 折叠

摘要

采用高温固相法合成了系列Sr2-xGa2SiO7:xSm3+红色荧光粉,通过X射线衍射(XRD)、扫描电子显微镜(SEM)、光致发光(PL)光谱、高温荧光光谱、荧光量子效率和荧光衰减寿命等一系列表征手段对合成荧光粉的物相及晶体结构、发光性能和热稳定性进行研究.一系列结果表明,在 404 nm紫外光激发下,Sr2-xGa2SiO7:xSm3+荧光粉在598 nm处发出明亮的红色光.Sr2-xGa2SiO7:xSm3+荧光粉发光强度随Sm3+离子浓度变化,在x=0.03时发生浓度猝灭,是由电偶极-电偶极相互作用导致的.随着温度逐渐上升,系列荧光粉表现出反常的热猝灭现象,在393 K时发光强度达到最大,强度为室温下的102.5%;在473 K时,发光强度仍可以保持室温下的101.3%.此外,最佳样品的荧光量子效率可达72.5%.研究表明,Sr2-xGa2SiO7:xSm3+红色荧光粉是一种具有高热稳定性、高量子效率可用于WLED的发光材料.

Abstract

A series of Sr2-xGa2SiO7:xSm3+red phosphors were synthesized using the high-temperature solid-phase method.The synthesized phosphors were characterized by X-ray diffraction(XRD),scanning electron microscopy(SEM),photoluminescence(PL)spectra,high-temperature luminescence spectra,fluorescence quantum efficien-cy,and fluorescence decay lifetime to investigate their phase composition,crystal structure,luminescent properties,and thermal stability.The results indicate that under 404 nm UV excitation,the Sr2-xGa2SiO7:xSm3+phosphors emit bright red light at 598 nm.The luminescence intensity of Sr2-xGa2SiO7:xSm3+phosphors varies with the concentration of Sm3+ions,exhibiting concentration quenching at x=0.03 due to dipole-dipole interactions.As the temperature in-creases,the phosphors display anomalous thermal quenching behavior,reaching maximum luminescence intensity at 393 K,which is 102.5%of that at room temperature.At 473 K,the luminescence intensity can still maintain 101.3%of that at room temperature.Additionally,the fluorescence quantum efficiency of the optimal sample can reach 72.5%.The research demonstrates that Sr2-xGa2SiO7:xSm3+red phosphors are promising luminescent materials for white light-emitting diodes(WLEDs)due to their high thermal stability and quantum efficiency.

关键词

反常热猝灭/高温固相法/硅酸盐/Sm3+掺杂

Key words

abnormal thermal quenching/high-temperature solid-state method/silicate/Sm3+doped

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出版年

2024
发光学报
中国物理学会发光分会,中国科学院长春光学精密机械与物理研究所

发光学报

CSTPCDCSCD北大核心
影响因子:1.301
ISSN:1000-7032
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