首页|C-S-H-PCE对基准水泥体系水化的影响

C-S-H-PCE对基准水泥体系水化的影响

Effect of C-S-H-PCE on hydration of reference cement system

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传统的早强剂在实际应用过程中会对混凝土的早强性能和耐久性能产生一定的影响,因此开发新型早强剂尤为重要.其中新开发的纳米C-S-H-PCE新型早强剂能够更好地加速水泥基材料的早期水化,有利于水化产物的快速生成.探究C-S-H-PCE早强剂对基准水泥体系水化的影响,对C-S-H-PCE的研发和应用具有重要意义.本文基于水泥水化的溶解-沉淀理论,研究C-S-H-PCE对基准水泥体系水化各阶段的影响,通过水化热测试对比分析C-S-H-PCE、纳米SiO2对水化历程的影响,并测定各阶段的凝结时间和抗压强度.结果表明,C-S-H-PCE的加入显著缩短水化诱导期、提高水化最大放热速率、促进未水化颗粒的溶解;C-S-H-PCE缩短了初凝和终凝时间,1d和3d的强度得到明显提升.由此可知C-S-H-PCE对基准水泥水化的作用规律和影响机制,从而建立了水化微结构和宏观力学性能之间的联系.
The traditional early strength agent will have some influence on the performance of concrete early strength anddurability in the practical application process,so it is necessary todevelop a new type of early strength agent.Among them,new type early strength of agentna-no-C-S-H-PCE can better accelerate the early hydration of cement-based materials,which is conducive to the rapid generation of hydra-tion products.It is of great significance for thedevelopment and application of C-S-H-PCE to explore the effect of C-S-H-PCE early strength agent on the hydration of reference cement system.Based on thedissolution-precipitation theory of cement hydration,this paper studies the effect of C-S-H-PCE on the hydration stages of the reference cement system.The effects of C-S-H-PCE and nano-SiO2 on the hydration process were compared and analyzed by hydration heat test,and the setting time and compressive strength of each stage were measured.The results showed that the addition of C-S-H-PCE significantly shortened the hydration induction period,increased the maximum heat release rate of hydration,and promoted thedissolution of unhydrated particles.C-S-H-PCE shortened the initial and final setting time,and the strength of 1d and 3d was significantly improved.It can be seen from this that the action law and influence mechanism of C-S-H-PCE on the hydration of reference cement,so as to establish the relationship between hydration microstructure and macroscopic mechanical properties.

C-S-H-PCE early strength agentstandard cement systemhydration heatcondensation timecompressive strengthnano-SiO2

陈星国

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福建省建筑科学研究院有限责任公司 福建省绿色建筑技术重点实验室 福建福州 350108

C-S-H-PCE早强剂 基准水泥体系 水化热 凝结时间 抗压强度 纳米SiO2

2024

福建建设科技
福建省建设厅科技情报中心站 福建省建筑科学研究院

福建建设科技

影响因子:0.5
ISSN:1006-3943
年,卷(期):2024.(4)