首页|CuSnTi复合钎料原位反应机制与接头组织性能

CuSnTi复合钎料原位反应机制与接头组织性能

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简化CuSnTi钎料制备流程、降低生产成本对高性能工具的发展至关重要.本文通过直接机械混合Cu、Sn、Ti单质金属粉制备CuSnTi钎料,并用于钎焊PcBN/YG8 异质材料,研究不同反应温度下CuSnTi钎料的微观组织演化,揭示钎焊过程中钎料的原位反应机制,并分析接头组织与性能.结果表明:CuSnTi钎料原位反应主要分为 3 个阶段:第一阶段,Sn熔化与Cu发生反应依次形成Cu6Sn5与Cu3Sn;第二阶段,Ti颗粒周围依次形成CuTi、Cu4Ti3、CuTi3 与CuSn3Ti5;第三阶段,液态钎料与石墨基体反应形成TiC,然后凝固析出不规则CuSn3Ti5.利用机械混合粉末钎料和合金粉钎料钎焊的PcBN/YG8 接头均为冶金结合,其剪切强度分别为 96.06 MPa和 91.40 MPa.机械混合粉末钎料钎焊的接头在PcBN处发生断裂,具有优良的力学性能.
In-situ reaction mechanism and joint microstructure and properties of CuSnTi composite brazing material
Simplifying the preparation process of CuSnTi solder and reducing production costs are crucial for the development of high-performance tools.In this paper,direct mechanical mixing technique of Cu,Sn,and Ti metal powders was employed to synthesize CuSnTi brazing materials,which was then used to brazed PcBN/YG8 heterogeneous materials.The evolution of microstructures of CuSnTi brazing materials at different reaction temperatures were studied,the in-situ reaction mechanism of brazing materials during the brazing process was revealed,and the microstructure and properties of joint were analyzed.The results show that the in-situ reaction of CuSnTi brazing material can be mainly divided into three stages:in the first stage,Sn melts and reacts with Cu to form Cu6Sn5 and Cu3Sn in sequence;in the second stage,CuTi,Cu4Ti3,CuTi3,and CuSn3Ti5 precipitate surrounding Ti particles in sequence;in the third stage,liquid brazing material reacts with graphite substrate leading to the formation of TiC,and then solidification and precipitation of irregular CuSn3Ti5.PcBN/YG8 joints brazed with mechanical mixed powder brazing material and alloy powder brazing material both have good metallurgical bonding,with shear strengths of 96.06 MPa and 91.40 MPa,respectively.The joint brazed with mechanical mixed powder brazing material breaks at the PcBN site and exhibits excellent mechanical properties.

CuSnTi composite brazing materialin-situ reactionmicroscopic morphologyjoint microstructuremechanical property

赵亦嘉、纠永涛、刘豪、陈正南、丁宗业、路全彬

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中国机械科学研究总院集团有限公司,北京 100044

宁波中机松兰刀具科技有限公司,宁波 315700

郑州机械研究所有限公司 新型钎焊材料与技术国家重点实验室,郑州 450001

CuSnTi复合钎料 原位反应 显微形貌 接头组织 力学性能

国家重点研发计划资助项目

2021YFB3401100

2024

粉末冶金材料科学与工程
中南大学

粉末冶金材料科学与工程

影响因子:0.578
ISSN:1673-0224
年,卷(期):2024.29(4)