首页|Cu-(石墨烯/6063A1)复合材料的设计制备及组织性能研究

Cu-(石墨烯/6063A1)复合材料的设计制备及组织性能研究

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以6063A1合金粉末、石墨烯纳米片和厚度为2 mm的纯Cu片为原材料,利用冷等静压+真空热压烧结+热挤压的方法制备了 Cu-6063A1复合材料含0.5%、1.0%(质量分数)石墨烯的Cu-(石墨烯/6063Al)复合材料.通过XRD、SEM和拉伸试验机对三种复合材料进行物相分析、微观组织和断口的SEM形貌表征及力学性能测试.试验结果表明:石墨烯/6063A1与Cu的冶金结合,能够有效抑制Al原子的扩散,从而对Cu-6063A1复合材料中Cu/Al界面处Al4Cu9、Al2Cu和AlCu三种金属间化合物的形成起到抑制作用.0.5%和1.0%含量的Cu-(石墨烯/6063A1)复合材料的抗拉强度为76.9 MPa和101.3 MPa,相比Cu-6063A1复合材料分别提高了 40%和83.8%,而伸长率均有所降低.Cu-(1.0%石墨烯/6063A1)复合材料具有优异的力学性能,一方面源于Cu/Al界面处少量的脆性相,另一方面源于靠近界面层的Al侧存在数量更多、尺寸更小、更深的韧窝、较宽的撕裂棱和更紧密结合、均匀分布的石墨烯纳米片.
Design,fabrication,microstructure and properties of Cu-(graphene/6063Al)composites
In this paper,the Cu-6063Al composites and 0.5%,1.0%content Cu-(graphene/6063Al)composites were fabricated by cold isostatic pressing+vacuum hot pressing sintering+hot extrusion method using 6063A1 al-loy powders,graphene nanosheets and pure Cu sheet with a thickness of 2 mm as raw materials.The phase analy-sis,microstructure,fracture characterization and mechanical properties of the three composites were investigated by XRD,SEM and tensile testing machine.The metallurgical composite of graphene/6063A1 and Cu can effective-ly inhibit the diffusion of Al atoms,and thus inhibit the formation of Al4Cu9,Al2Cu 和 AlCu intermetallic com-pounds at the Cu/Al interface in Cu-6063A1 composites.The tensile strength of 0.5%and 1.0%Cu-(graphene/6063A1)composites is 76.9 MPa and 101.3 MPa,which are 40%and 83.8%higher than that of Cu-6063A1 com-posites respectively,and the elongation is decreased.The Cu-(1.0%graphene/6063Al)composite possess excellent mechanical properties,due to a small amount of brittle phase at the Cu/Al interface and more,smaller,deeper dim-ples,wider tearing edges and tighter distribution of graphene nanosheets near the interface layer of Al side.

graphene nanosheetCu-(graphene/Al)compositeinterface layerprecipitatefracture morphology

张可萌、柳培、王杰、侯博、刘振伟、高岩

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河南科技大学材料科学与工程学院,河南洛阳 471023

有色金属新材料及先进加工技术省部共建协同创新中心,河南洛阳 471023

河南省冶金研究所有限责任公司,河南郑州 450000

石墨烯纳米片 Cu-(石墨烯/A1)复合材料 界面层 析出相 断口形貌

河南省科学院科研开发专项

220910009

2024

粉末冶金工业
中国钢研科技集团有限公司 中国钢协粉末冶金分会 中国机协粉末冶金分会

粉末冶金工业

CSTPCD北大核心
影响因子:0.406
ISSN:1006-6543
年,卷(期):2024.34(2)
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