福州大学学报(自然科学版)2024,Vol.52Issue(3) :299-306.DOI:10.7631/issn.1000-2243.23050

含生活垃圾焚烧炉渣的碱矿渣水泥耐高温机理

Research on high temperature resistance mechanism of alkali-activated slag paste containing municipal solid waste incineration bottom ash

张彬彬 马宇 梁咏宁 林毅武 季韬
福州大学学报(自然科学版)2024,Vol.52Issue(3) :299-306.DOI:10.7631/issn.1000-2243.23050

含生活垃圾焚烧炉渣的碱矿渣水泥耐高温机理

Research on high temperature resistance mechanism of alkali-activated slag paste containing municipal solid waste incineration bottom ash

张彬彬 1马宇 1梁咏宁 1林毅武 2季韬1
扫码查看

作者信息

  • 1. 福州大学土木工程学院,福建 福州 350108
  • 2. 厦门正欣茂建设工程有限公司,福建 厦门 361101
  • 折叠

摘要

为探究生活垃圾焚烧炉渣(MSWI-BA)对碱矿渣净浆耐高温性能的影响机理,将 6%的矿渣等质量替换为MSWI-BA,制备碱矿渣水泥净浆(AASBp),研究不同温度对AASBp的质量损失率、干燥收缩率和强度的影响.以普通硅酸盐水泥净浆作为对照组,结合多种微观手段,揭示AASBp的耐高温机理,并与未掺MSWI-BA的碱矿渣水泥(AASp)进行对比.结果表明:随着温度的升高,AASBp中水化硅铝酸钙的钙硅比(C/S)先降低后升高;在 400℃时,水化硅铝酸钙的聚合度最高,C/S最低;Al—O键在 600℃断裂,而Si—O键在 1 000℃断裂;MSWI-BA可提高基体孔隙的连通性,高温处理后孔隙压力得到释放,因此AASBp比AASp具有更高的归一化抗压强度和耐高温性能.

Abstract

In order to investigate the influence mechanism of municipal solid waste incineration bottom ash(MSWI-BA)on the high temperature resistance of alkali-activated slag paste,6%slag was replaced with the equal mass of MSWI-BA to prepare alkali-activated slag paste with MSWI-BA(AASBp).The effects of different temperatures on the mass loss rate,thermal shrinkage rate and strength of AASBp were studied.Ordinary Portland cement paste was used as a control group.The high-temperature resistance mechanism of AASBp was revealed by multiple microscopic approaches,and compared with alkali-activated slag paste without MSWI-BA(AASp).The results show that the calcium-to-silicon ratio(C/S)of calcium aluminosilicate hydrate of AASBp decreases first and then increases with an increase in temperature;at 400℃,the polymerization degree of calcium aluminosili-cate hydrate is the highest and C/S is the lowest.The Al—O bond breaks at 600℃,while the Si—O bond breaks at 1 000℃.Compared with AASp,AASBp has higher normalized compressive strength and better high-temperature resistance because MSWI-BA improves the connectivity of matrix pores and releases pore pressure after high temperature treatment.

关键词

碱激发矿渣/生活垃圾焚烧炉渣/耐高温/干燥收缩率/水化硅铝酸钙的聚合度

Key words

alkali-activated slag/municipal solid waste incineration bottom ash/high-temperature resistance/thermal shrinkage/polymerization degree of calcium aluminosilicate hydrate

引用本文复制引用

基金项目

国家自然科学基金(52278248)

福建省自然科学基金重点项目(2021J02021)

出版年

2024
福州大学学报(自然科学版)
福州大学

福州大学学报(自然科学版)

CSTPCD北大核心
影响因子:0.35
ISSN:1000-2243
参考文献量4
段落导航相关论文