福州大学学报(自然科学版)2024,Vol.52Issue(6) :717-723.DOI:10.7631/issn.1000-2243.23409

煅烧硅藻土对UHPC收缩性能的影响及机理

Influence and mechanism of calcined diatomaceous on shrinkage performance of UHPC

梁咏宁 钱乾 肖泽荣 吴明勤 陈志斌 季韬
福州大学学报(自然科学版)2024,Vol.52Issue(6) :717-723.DOI:10.7631/issn.1000-2243.23409

煅烧硅藻土对UHPC收缩性能的影响及机理

Influence and mechanism of calcined diatomaceous on shrinkage performance of UHPC

梁咏宁 1钱乾 2肖泽荣 3吴明勤 2陈志斌 4季韬5
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作者信息

  • 1. 福州大学先进制造学院,福建 泉州 362251;福州大学土木工程学院,福建 福州 350108
  • 2. 福州大学先进制造学院,福建 泉州 362251
  • 3. 福州市规划设计研究院集团有限公司,福建 福州 350108
  • 4. 福建海峡环保资源开发有限公司,福建 福州 350108
  • 5. 福州大学土木工程学院,福建 福州 350108
  • 折叠

摘要

利用煅烧硅藻土(calcined diatomaceous,CD)取代部分水泥制备超高性能混凝土(UHPC),研究煅烧硅藻土掺量对UHPC自收缩和干燥收缩的影响,通过内部相对湿度、压汞法和微观形貌解释其对UHPC收缩性能的影响机理.实验结果表明,多孔结构的煅烧硅藻土在浆体搅拌过程中可以吸收自由水,并在前期水泥水化的过程中释放出来,具有良好的内养护功能;随着煅烧硅藻土掺量(质量分数 0~15%)的增加,UHPC早期抗压强度略微下降,后期抗压强度变化不大,浆体内部相对湿度逐渐增加,10~50 nm和小于 100 nm的孔隙逐渐减少,UHPC的自收缩和干燥收缩逐渐降低,其中煅烧硅藻土掺量为 15%时自收缩和干燥收缩最低;与未掺煅烧硅藻土的UHPC相比,掺 15%煅烧硅藻土的UHPC 7 d自收缩率降低 27.0%,90 d干燥收缩率下降 31.0%.

Abstract

In this paper,the influence of the dosage of calcined diatomite on the autogenous and drying shrinkage of ultra-high performance concrete(UHPC)was investigated by using calcined diato-maceous as a partial replacement for cement in the preparation of UHPC.The influence mechanism of calcined diatomite on the shrinkage performance of UHPC was explained by internal relative humidity,mercury intrusion method and microstructure.The results showed that calcined diatomite,which has porous structure and effective internal curing function,can absorb free water during the slurry mixing process and subsequently release it during the early stages of cement hydration.XRD of calcined diatomite with the increase of calcined diatomite content(0 to 15%,mass fraction),the compressive strength of UHPC in the early stage decreased slightly,and the compressive strength of UHPC in the later stage did not change much.The relative humidity inside the slurry gradually increased,the pores of 10 to 50 nm and less than 100 nm gradually decreased,and the autogenous shrinkage and drying shrinkage of UHPC gradually decreased.When the content of calcined diatomite is 15%,the autoge-nous shrinkage and drying shrinkage are the lowest.Compared with UHPC without calcined diatomite,the 7 d autogenous shrinkage value of UHPC with 15%calcined diatomite decreased by 27.0%,and the 90 d drying shrinkage decreased by 31.0%.

关键词

超高性能混凝土/煅烧硅藻土/孔结构/自收缩/干燥收缩

Key words

ultra-high performance concrete/calcined diatomite/pore structure/autogenous shrink-age/drying shrinkage

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出版年

2024
福州大学学报(自然科学版)
福州大学

福州大学学报(自然科学版)

CSTPCD北大核心
影响因子:0.35
ISSN:1000-2243
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