首页|原位合成Al2O3/TiB2颗粒混杂增强铝基复合材料的性能研究

原位合成Al2O3/TiB2颗粒混杂增强铝基复合材料的性能研究

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针对传统铝合金无法满足工业和民用中对高强高导铝合金需求的问题,开发一种提升铝合金表面硬度且保证其导电导热性能的新型铝基复合材料.通过机械合金化法制备了 Al-TiO2-B混合粉末,采用放热弥散结合接触反应技术成功原位合成Al2O3/TiB2颗粒混杂增强铝基复合材料,探究了原始粉末Al-TiO2-B体系反应生成Al2O3/TiB2颗粒混杂增强铝基复合材料的反应机理及反应温度对原位反应的影响,分析了铝基复合材料的微观组织形貌以及表面显微硬度和导电导热性能.XRD分析结果表明,反应温度达到1 100 ℃保温200 min后,原始粉末Al-TiO2-B体系中的TiO2和B粉末完全反应,并且在反应过程中B粉抑制了中间产物Al3Ti和AlB2的生成,最终原位生成为Al2O3和TiB2颗粒混杂增强的铝基复合材料.显微组织观察表明,在铝基体中原位生成了 TiB2颗粒(直径小于1 µm)和Al2O3颗粒(粒径约为2 μm),且铝基复合材料表面组织均匀致密.原位合成Al2O3/TiB2混杂颗粒增强铝基复合材料的电导率为46.1%IACS,热导率约为198.5 W·m-1·K-1,显微硬度较传统A356铝合金的68 HV提升至76 HV,新型原位合成铝基复合材料在保证导电导热性能的前提下提升了铝基复合材料的显微硬度.
Property study of Al2O3/TiB2 particle hybrid reinforced aluminum matrix composite by in-situ synthesis
This study aims to develop a novel aluminum matrix composite material that enhances surface hardness while maintaining its electrical and thermal conductivity properties to meet the demands of industrial and civilian applications,given the inadequacies of traditional aluminum alloys.Through mechanical alloying,Al-TiO2-B hybrid powders were prepared,and an in-situ synthesis of Al2O3/TiB2 particulate hybrid-reinforced aluminum matrix composite material was achieved using exothermic dispersion bonding contact reaction technique.The research investigates the reaction mechanism of the Al-TiO2-B system to generate Al2O3/TiB2 particulate hybrid-reinforced aluminum matrix composite material and the influence of reaction temperature on in-situ reaction.Microstructural morphology,surface microhardness,and electrical and thermal conductivity properties of the alu-minum matrix composite material were studied.XRD analysis revealed that at a reaction temper-ature of 1 100 ℃ and a holding time of 200 minutes,complete reaction of TiO2 and B powders in the Al-TiO2-B system occurred,with B powder inhibiting the formation of intermediate products Al3Ti and A1B2 during the reaction process,resulting in the in-situ generation of Al2O3 and TiB2 particulate hybrid-reinforced aluminum matrix composite material.Microstructural observation demonstrated the in-situ generation of TiB2 particles(diameter less than 1 pm)and Al2 O3 parti-cles(approximately 2 pm in diameter)within the aluminum matrix,with a uniformly dense sur-face structure of the aluminum matrix composite material.The electrical conductivity of the in-si-tu synthesized Al2O3/TiB2 hybrid particle-reinforced aluminum matrix composite material was 46.1%IACS,and the thermal conductivity was approximately 198.5 W·m-1·K-1,with the mi-crohardness increasing from 68 HV(for traditional A356 aluminum alloy)to 76 HV.This novel in-situ synthesized aluminum matrix composite material enhances microhardness while ensuring electrical and thermal conductivity properties.

in situ synthesisaluminum matrix compositeAl2O3/TiB2hybrid particle reinforce-ment

王军、王俊、王应、张文逸、龙洲、张慧敏、李智国

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西安工程大学材料工程学院,陕西西安 710048

原位合成 铝基复合材料 Al2O3/TiB2 混杂颗粒增强

陕西省自然科学基金重点研发计划

2023-YBGY-171

2024

纺织高校基础科学学报
西安工程大学 全国纺织教育学会

纺织高校基础科学学报

CSTPCD
影响因子:0.339
ISSN:1006-8341
年,卷(期):2024.37(2)
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