首页|可生物降解聚乳酸长丝的熔融纺丝工艺

可生物降解聚乳酸长丝的熔融纺丝工艺

Melt spinning process of biodegradable PLA filaments

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为了纺制高品质的聚乳酸长丝,采用熔融纺丝方法,优化切片干燥工艺,研究了纺丝工艺参数(纺丝温度、纺丝速度、拉伸倍数、拉伸温度)对聚乳酸长丝性能(黏均分子质量、取向、力学性能等)的影响,最终确定了最佳的纺丝工艺.最优的切片干燥工艺为:分2阶段进行干燥,第1阶段由室温逐步升温至60 ~ 65℃,停留3~4h预结晶,第2阶段逐步升温至100℃干燥15 h,最终切片含水率低于0.005%.最佳纺丝工艺为:纺丝温度195℃,纺丝速度1 000 m/min,拉伸3倍,拉伸温度T1/T2/T3 =72℃/80℃/82℃.
In order to spin the high quality PLA filaments, the melt spinning method was adopted and the chip drying process was optimized. The effects of spinning parameters, including spinning temperature and speed, stretching ratio and temperature, on the performance of PLA filament ( viscosity average molecular weight, orientation and mechanical property) were also researched. The results indicated that the PLA chip should be dried in two stages. At the first stage, the temperature should climb up to 60-65℃. and was held for 3 - 4 h, in order to pre-crystallize, and at the second stage, the drying temperature rose up to 100 ℃. and was held for 15 h. Finally, the chip moisture content should be lower than 0.005%. The optimum spinning parameters were as follows: spinning temperature 195℃ , spinning speed 1 000 m/min, stretching ratio 3 and stretching temperature T1/T2/T3 = 72℃/80℃/82℃.

PLA filamentmelt-spinningchip dryingspinning speedstretching

刘淑强、张蕊萍、贾虎生、戴晋明、刘旭光、许并社

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太原理工大学材料科学与工程学院,山西太原030024

太原理工大学轻纺工程与美术学院,山西晋中030600

新材料界面科学与工程教育部重点实验室(太原理工大学),山西太原030024

聚乳酸长丝 熔融纺丝 切片干燥 纺丝速度 拉伸

教育部长江学者和创新团队发展计划国家自然科学基金太原理工大学校青年基金

IRT097250943027K201029

2012

纺织学报
中国纺织工程学会

纺织学报

CSTPCDCSCD北大核心
影响因子:0.699
ISSN:0253-9721
年,卷(期):2012.33(11)
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