纺织学报2022,Vol.43Issue(10) :112-118,125.DOI:10.13475/j.fzxb.20210805808

氮碳量子点/二氧化钛复合整理粘胶织物光催化协同构效

Photocatalytic synergistic efficiency of viscose fabric loaded with nitrogen carbon quantum dots/titanium dioxide

冯艳 李亮 刘淑萍 李淑静 刘让同
纺织学报2022,Vol.43Issue(10) :112-118,125.DOI:10.13475/j.fzxb.20210805808

氮碳量子点/二氧化钛复合整理粘胶织物光催化协同构效

Photocatalytic synergistic efficiency of viscose fabric loaded with nitrogen carbon quantum dots/titanium dioxide

冯艳 1李亮 2刘淑萍 1李淑静 1刘让同1
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作者信息

  • 1. 纺织服装产业河南省协同创新中心,河南 郑州 450007;河南省功能纺织材料重点实验室,河南 郑州450007;中原工学院 服装学院,河南 郑州 450007
  • 2. 纺织服装产业河南省协同创新中心,河南 郑州 450007;河南省功能纺织材料重点实验室,河南 郑州450007;中原工学院 纺织学院,河南 郑州 450007
  • 折叠

摘要

为提高服装面料在太阳光下的光催化自清洁性能,采用柠檬酸和尿素制备氮碳量子点( N-CQDs) ,并通过水热法与纳米二氧化钛( TiO2 )共同整理粘胶织物,制备出太阳光响应复合光催化纺织品。 借助扫描电子显微镜、红外光谱仪、紫外-可见分光光度计等对整理前后的粘胶织物进行表征,测试其光学吸收性、光催化降解脱色性和稳定性,研究N-CQDs、TiO2 及其复合体系降解罗丹明B的协同构效机制。 结果表明:在模拟日光下催化降解罗丹明B 5 h时,经N-CQDs/TiO2 整理的粘胶织物脱色率为76. 5%,比经TiO2 整理粘胶织物的脱色率( 51. 3%)提高了49. 1%,且循环降解6次后,脱色率仍能达到62. 34%。

Abstract

In order to improve the self-cleaning performance of clothing fabrics under sunlight, nitrogen-doped carbon quantum dots ( N-CQDs) were prepared from citric acid and urea, and the composite photocatalytic textiles were created through hydrothermal treatment of viscose fabrics loaded with nitrogen-doped carbon quantum dots and nano titanium dioxide. The viscose fabrics were characterized by means of scanning electron microscope, infrared spectrometer, and ultraviolet-visible photometer, and heir optical absorption, photocatalytic degradation and stability were tested. The synergistic mechanism of degradation of Rhodamine B ( RhB) by N-CQDs, TiO2 and their composite systems were studied. The results show that the decolorization rate of fabric loaded with N-CQDs/TiO2 is 76. 5%, which is 49. 1% higher than that of fabric loaded with TiO2 , and the decolorization rate can still reach 62. 34% after 6 cycles of photocatalytic degradation of RhB.

关键词

粘胶织物/氮掺杂碳量子点/二氧化钛/太阳光催化降解/协同机制

Key words

viscose fabric/nitrogen doped carbon quantum dots/titanium dioxide/solar photocatalytic degradation/synergistic mechanism

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基金项目

国家重点研发计划项目(2017YFB0309100)

出版年

2022
纺织学报
中国纺织工程学会

纺织学报

CSTPCDCSCD北大核心
影响因子:0.699
ISSN:0253-9721
参考文献量9
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