首页|[H2dab][GaB5O10]:an Acentric Galloborate with a 4-Connected Uninodal Framework

[H2dab][GaB5O10]:an Acentric Galloborate with a 4-Connected Uninodal Framework

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A new acentric galloborate(GBO)[H2dab][GaB5O10](1,1,4-dab:1,4-diaminobutane)has been synthesized under solvothermal conditions.The alternation of 4,4-connected GaO4 and B5O10 cluster build up the 3D[GaB5O10]n2n-uninodal framework,which contains three pairs of helical channels with 8-member ring(MR)and 7-MR apertures,respectively.Compound 1 exhibits a moderate second harmonic generation(SHG)response of 1.8 times that of KH2PO4(KDP),indicating its potential application in UV regions.The acentric uninodal framework in compound 1 represents a new type of zeolitic framework in the GBOs'family.

GalloborateSolvothermal synthesisNonlinear opticsZeolitic framework

LIU Wenfang、CHEN Chongan、YANG Guoyu

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School of Chemistry and Chemical Engineering,Beijing Institute of Technology,Beijing 102488,P.R.China

National Natural Science Foundation of ChinaNational Natural Science Foundation of ChinaNational Natural Science Foundation of ChinaNational Natural Science Foundation of China for Distinguished Young Scholars

21831001215710169112202820725101

2024

10.1007/s40242-024-4130-5

高等学校化学研究(英文版)
吉林大学

高等学校化学研究(英文版)

CSTPCD
影响因子：0.871
ISSN：1005-9040
年,卷(期)：2024.40(4)