首页|Advancements and Prospects in Continuous Wave Time-resolved Electron Paramagnetic Resonance

Advancements and Prospects in Continuous Wave Time-resolved Electron Paramagnetic Resonance

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This brief review highlights the techniques and diverse applications of time-resolved electron paramagnetic resonance(TREPR)spectroscopy,underscoring its essential role in elucidating the structures,spin dynamics,and reactivities of open-shell systems.Furthermore,we discuss the limitations of traditional TREPR methodologies,particularly their challenges in directly observing reactive radical intermediates under real-world reaction conditions.Lastly,we present the latest advancements in TREPR technology developed in our laboratory,specifically ultrawide single-sideband phase-sensitive detection(U-PSD)TREPR,highlighting its significant impact and tremendous potential in advancing free radical chemistry research.We envision promising future applications of TREPR and its pivotal role in enhancing our understanding of mechanisms involved in complex radical processes and photocatalysis.

Time-resolved electron paramagnetic resonance(TREPR)Ultrawide single-sideband phase-sensitive detection(U-PSD)Spin chemistryRadical chemistryPhotochemistry

ZHANG Shixue、ZHOU Shengqi、WU Hao、GUO Xingwei

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Center of Basic Molecular Science(CBMS),Department of Chemistry,Tsinghua University,Beijing 100084,P.R.China

Tsinghua University Dushi Program,China

52308013422

2024

高等学校化学研究(英文版)
吉林大学

高等学校化学研究(英文版)

CSTPCD
影响因子:0.871
ISSN:1005-9040
年,卷(期):2024.40(5)