高等学校化学研究(英文版)2024，Vol.40Issue(5) ：863-873.DOI:10.1007/s40242-024-0095-4

Visible-light-induced Synthesis of Organic Peroxides via Decarboxylative Couplings of Carboxylic Acids,Alkenes and tert-Butyl Hydroperoxide

HUANG Qiuwei LOU Chenhao LV Leiyang LI Zhiping
高等学校化学研究(英文版)2024，Vol.40Issue(5) ：863-873.DOI:10.1007/s40242-024-0095-4
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Visible-light-induced Synthesis of Organic Peroxides via Decarboxylative Couplings of Carboxylic Acids,Alkenes and tert-Butyl Hydroperoxide

HUANG Qiuwei 1LOU Chenhao 1LV Leiyang 1LI Zhiping1
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作者信息

  • 1. Key Laboratory of Advanced Light Conversion Materials and Biophotonics,School of Chemistry and Life Resources,Renmin University of China,Beijing 100872,P.R.China
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Abstract

Herein,we present a photoinduced,CeCl3-catalyzed three-component decarboxylative reaction that couples carboxylic acids,alkenes and tert-butyl hydroperoxide for the formation of various organic peroxides.The ligand-to-metal charge transfer(LMCT)excitation mode allows the decarboxylative alkylation-peroxidation reaction to occur under mild conditions,and is well applicable to primary,secondary and tertiary carboxylic acids and styrene derivatives.

Key words

Visible-light catalysis/Difunctionalization/Carboxylic acid/Alkene/Organic peroxide

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基金项目

National Natural Science Foundation of China(22071266)

National Natural Science Foundation of China(22201300)

出版年

2024
高等学校化学研究(英文版)
吉林大学

高等学校化学研究(英文版)

CSTPCD
影响因子：0.871
ISSN：1005-9040
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