首页|Visible-light-induced Synthesis of Organic Peroxides via Decarboxylative Couplings of Carboxylic Acids,Alkenes and tert-Butyl Hydroperoxide
Visible-light-induced Synthesis of Organic Peroxides via Decarboxylative Couplings of Carboxylic Acids,Alkenes and tert-Butyl Hydroperoxide
扫码查看
点击上方二维码区域,可以放大扫码查看
原文链接
NETL
NSTL
万方数据
Herein,we present a photoinduced,CeCl3-catalyzed three-component decarboxylative reaction that couples carboxylic acids,alkenes and tert-butyl hydroperoxide for the formation of various organic peroxides.The ligand-to-metal charge transfer(LMCT)excitation mode allows the decarboxylative alkylation-peroxidation reaction to occur under mild conditions,and is well applicable to primary,secondary and tertiary carboxylic acids and styrene derivatives.
Key Laboratory of Advanced Light Conversion Materials and Biophotonics,School of Chemistry and Life Resources,Renmin University of China,Beijing 100872,P.R.China
National Natural Science Foundation of ChinaNational Natural Science Foundation of China