首页|Visible-light-induced Synthesis of Organic Peroxides via Decarboxylative Couplings of Carboxylic Acids,Alkenes and tert-Butyl Hydroperoxide

Visible-light-induced Synthesis of Organic Peroxides via Decarboxylative Couplings of Carboxylic Acids,Alkenes and tert-Butyl Hydroperoxide

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Herein,we present a photoinduced,CeCl3-catalyzed three-component decarboxylative reaction that couples carboxylic acids,alkenes and tert-butyl hydroperoxide for the formation of various organic peroxides.The ligand-to-metal charge transfer(LMCT)excitation mode allows the decarboxylative alkylation-peroxidation reaction to occur under mild conditions,and is well applicable to primary,secondary and tertiary carboxylic acids and styrene derivatives.

Visible-light catalysisDifunctionalizationCarboxylic acidAlkeneOrganic peroxide

HUANG Qiuwei、LOU Chenhao、LV Leiyang、LI Zhiping

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Key Laboratory of Advanced Light Conversion Materials and Biophotonics,School of Chemistry and Life Resources,Renmin University of China,Beijing 100872,P.R.China

National Natural Science Foundation of ChinaNational Natural Science Foundation of China

2207126622201300

2024

高等学校化学研究(英文版)
吉林大学

高等学校化学研究(英文版)

CSTPCD
影响因子:0.871
ISSN:1005-9040
年,卷(期):2024.40(5)