首页|Synthesis and Properties of Ferrocene Conjugated Macrocycles with Illusory Topology of the Penrose Stairs
Synthesis and Properties of Ferrocene Conjugated Macrocycles with Illusory Topology of the Penrose Stairs
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Polyferrocene macrocycles hold immense potential in the fields of molecular electronics and electrochemistry,primarily due to their multiple metal centers.However,developing highly efficient synthetic strategies for constructing these rings remains a significant challenge.In this study,we successfully synthesized tri-ferrocenyl macrocycles using Pt-mediated coupling strategy and determined their configuration using single-crystal X-ray diffraction analysis,revealing a structure reminiscent of the Penrose Stair.We comprehensively investigated the macrocycle's structure,photophysical properties,and employed density functional theory(DFT)calculations to gain further insights.Notably,this macrocycle exhibits several advantageous features,including a flexible structure,good solubility,and a highly efficient synthetic pathway.
Key Laboratory of Molecule Synthesis and Function Discovery(Fujian Province University),College of Chemistry,Fuzhou University,Fuzhou 350108,P.R.China
Henan Key Laboratory of Biomolecular Recognition and Sensing,College of Chemistry and Chemical Engineering,Shangqiu Normal University,Shangqiu 476000,P.R.China
National Natural Science Foundation of ChinaNational Natural Science Foundation of ChinaKey Research and Development and Promotion Projects in Henan Province,China
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