首页|CaCO3/Ag2O复合光催化剂降解及抗菌性能研究

CaCO3/Ag2O复合光催化剂降解及抗菌性能研究

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为提高CaCO3的使用率,拓展其在处理污染物及抗菌方面的应用,利用沉淀法合成Ag2O及添加CaCO3进一步制备CaCO3/Ag2O光催化剂,通过XRD、XPS、SEM、TEM等对其结构组成、形貌晶格等方面进行表征.实验结果表明,当CaCO3与Ag2O复合比例为1∶1时,在可见光下30 min内对亚甲基蓝降解率可达90%,同时4次循环实验也表明,CaCO3/Ag2O复合光催化剂具有良好的稳定性.光催化剂抗菌试验表明,CaCO3/Ag2O复合光催化剂在30 min内可将金黄色葡萄球菌全部清除.CaCO3负载Ag2O形成异质结,促进了光生电子空穴对的分离,有效提高了复合体系光催化性能.
Degradation and antibacterial properties of CaCO3/Ag2O composite photocatalyst
In order to improve the utilization of CaCO3 and expand its application in pollutant treatment and antibacterial,Ag2O was synthesized by precipitation method and CaCO3 was added to further prepare CaCO3/Ag2O photocatalyst.The structural composi-tion and morphological lattice were characterized by XRD,XPS,SEM,TEM.The experimental results show that when the molar ra-tio of CaCO3 to Ag2O is 1∶1,the degradation rate of methylene blue can reach 90%within 30 min under visible light.The subse-quent four cycle experiments also show that the CaCO3/Ag2O composite photocatalyst has good stability.The antibacterial test of photocatalyst shows that the CaCO3/Ag2O composite photocatalyst can completely eliminate Staphylococcus aureus within 30 min.Ag2O supported by CaCO3 forms a heterojunction,which promotes the separation of photogenerated electron-hole pairs and effec-tively improves the photocatalytic performance of the composite system.

photocatalysisCaCO3/Ag2Ochemical precipitation methodmethylene blueantibacterialdegradation

徐凤、钟燕、王殿辉、胡朝浩

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桂林电子科技大学材料科学与工程学院,广西桂林 541004

光催化 CaCO3/Ag2O 沉淀法 亚甲基蓝 抗菌 降解

2024

桂林电子科技大学学报
桂林电子科技大学

桂林电子科技大学学报

影响因子:0.247
ISSN:1673-808X
年,卷(期):2024.44(3)