首页|TiO2改性钢渣基透水混凝土的力学和NOx降解性能研究

TiO2改性钢渣基透水混凝土的力学和NOx降解性能研究

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以内掺纳米TiO2为光催化剂,钢渣和矿渣粉为胶材,大钢渣颗粒为骨料,制备了 TiO2改性钢渣基透水混凝土(TSSPC),并研究了 TiO2掺量对TSSPC的抗压强度、透水性能和NO,降解性能的影响.此外,结合XRD和SEM-EDX等微观测试分析方法,阐明了 TiO2对TSSPC力学性能、透水性能和光催化性能的影响机理,为TiO2在透水混凝土中的应用奠定了基础.结果表明,当TiO2掺量较少时,TiO2颗粒的"晶核效应"对胶凝材料的早期水化有促进作用.但当TiO2掺量较多时,TiO2颗粒易发生团聚,不利于TSSPC的力学性能发展.此外,随着TiO2掺量的提高,透水混凝土的连通孔隙率和透水系数均上升.相较于空白对照组,TiO2掺量为5%(质量分数,下同)的TSSPC的连通孔隙率和透水系数分别提高了 4.5个百分点和1.34 mm·s-1.TSSPC对NOx的降解效率随着TiO2掺量(0%~5%)的增加而提高,当TiO2掺量超过3%时,继续增加TiO2掺量对NOx降解效率的提升效果显著下降.
Mechanical and NOx Degradation Performance of TiO2 Modified Steel Slag-Based Permeable Concrete
TiO2 modified steel slag-based permeable concrete(TSSPC)was prepared with nano-TiO2 incorporated as photocatalyst,steel slag and slag powder as binder,and large steel slag particle as aggregate.The effects of TiO2 content on the compressive strength,water permeability and NOx degradation performance of TSSPC were studied.In addition,combined with microscopic test and analysis methods such as XRD and SEM-EDX,the effect mechanism of TiO2 on the mechanical properties,water permeability and photocatalytic performance of TSSPC was investigated,laying the foundation for the application of TiO2 in permeable concrete.The results show that when the TiO2 content is low,the"nucleation effect"of TiO2 particles promotes the early hydration of binder materials.However,when TiO2 content is high,TiO2 particles tend to agglomerate,which is harmful to the mechanical properties of TSSPC.In addition,as the TiO2 content increases,the connected porosity and water permeability coefficient of permeable concrete increase.Compared with the blank control group,the connected porosity and water permeability coefficient of TSSPC with a TiO2 content of 5%(mass fraction,the same below)increase by 4.5 percentage points and 1.34 mm·s-1,respectively.The NOx degradation efficiency of TSSPC increases as the TiO2 content(0%~5%)increases.However,due to the agglomeration phenomenon,when the TiO2 content exceeds 3%,the effect of increasing the TiO2 content on NOx degradation efficiency decreases significantly.

steel slagpermeable concreteTiO2mechanical propertyNOx degradation

林元明、林佳福、熊晓立、杨政险

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福州第七建筑工程有限公司,福州 350013

福州大学土木工程学院,福州 350108

钢渣 透水混凝土 TiO2 力学性能 NOx降解

国家自然科学基金福州市科技局科技创新平台项目校企合作项目(新型低碳环保光催化混凝土材料的研发及应用)

519781712021-P-031

2024

硅酸盐通报
中国硅酸盐学会 中材人工晶体研究院

硅酸盐通报

CSTPCD北大核心
影响因子:0.698
ISSN:1001-1625
年,卷(期):2024.43(1)
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